[Wien] ROTDEF - Error found in AFM calculations

Peter Blaha pblaha at theochem.tuwien.ac.at
Mon Apr 23 14:19:05 CEST 2007


I could not really reproduce the problem you mentioned.
Nevertheless I found a related problem when I do not have a supergroup file
(the case.inclmcopy_st file is incomplete!).

There is a small bug in afminput.f, which in some cases could lead to a problem:
...
!      Ensure that lsymm has unitary as first -- for simplicity
        do j=1,iord1

In the last line it should be iord and NOT iord1 !

Regards


Lei Liu schrieb:
>   
>  Dear   Wien users,
> 
>  I found ROTDEF - Error may exit during AFM calculations for quite some structures. It bore me so much that I have to report the error again.
> Could anyone please give me some suggestions or try such structures in your system? Your help would be highly appreciated.
> 
> The normal error message is something like, after I run runafm_lapw:
>  'ROTDEF' - no symmetry operation found.
>  'ROTDEF' - for jatom, index 514
>  'ROTDEF' - atomposition of jatom   0.5000000   0.5000000   0.5000000
>  'ROTDEF' - atomposition of index   0.0000000   0.0000000   0.5000000
> 
> I attact my  input files of two test models as below. I use the version WIEN2k_07.2  compiled with intel ifort  9.0 and MKL8.1.
> 
> 
> 
> Many thanks,
> Lei LIU
> 
> .struct file
> 
> test3-afm                                                   
> P   LATTICE,NONEQUIV.ATOMS: 11 115 P-4m2
> MODE OF CALC=RELA unit=bohr
>  15.119510 15.119510 22.676714 90.000000 90.000000 90.000000
> ATOM   1: X=0.00000000 Y=0.00000000 Z=0.00000000
>           MULT= 1          ISPLIT= 5
> Cu1        NPT=  781  R0=0.00005000 RMT=    2.4900   Z: 29.0
> LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
>                      0.0000000 1.0000000 0.0000000
>                      0.0000000 0.0000000 1.0000000
> ATOM   2: X=0.50000000 Y=0.50000000 Z=0.50000000
>           MULT= 1          ISPLIT= 5
> Cu2        NPT=  781  R0=0.00005000 RMT=    2.4900   Z: 29.0
> LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
>                      0.0000000 1.0000000 0.0000000
>                      0.0000000 0.0000000 1.0000000
> ATOM   3: X=0.25000000 Y=0.25000000 Z=0.75000000
>           MULT= 8          ISPLIT= 5
>        3: X=0.75000000 Y=0.75000000 Z=0.75000000
>        3: X=0.25000000 Y=0.75000000 Z=0.25000000
>        3: X=0.75000000 Y=0.25000000 Z=0.25000000
>        3: X=0.25000000 Y=0.75000000 Z=0.75000000
>        3: X=0.75000000 Y=0.25000000 Z=0.75000000
>        3: X=0.25000000 Y=0.25000000 Z=0.25000000
>        3: X=0.75000000 Y=0.75000000 Z=0.25000000
> Zn1        NPT=  781  R0=0.00005000 RMT=    2.4900   Z: 30.0
> LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
>                      0.0000000 1.0000000 0.0000000
>                      0.0000000 0.0000000 1.0000000
> ATOM   4: X=0.50000000 Y=0.00000000 Z=0.00000000
>           MULT= 2          ISPLIT= 5
>        4: X=0.00000000 Y=0.50000000 Z=0.00000000
> Zn2        NPT=  781  R0=0.00005000 RMT=    2.4900   Z: 30.0
> LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
>                      0.0000000 1.0000000 0.0000000
>                      0.0000000 0.0000000 1.0000000
> ATOM   5: X=0.00000000 Y=0.50000000 Z=0.50000000
>           MULT= 2          ISPLIT= 5
>        5: X=0.50000000 Y=0.00000000 Z=0.50000000
> Zn3        NPT=  781  R0=0.00005000 RMT=    2.4900   Z: 30.0
> LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
>                      0.0000000 1.0000000 0.0000000
>                      0.0000000 0.0000000 1.0000000
> ATOM   6: X=0.00000000 Y=0.00000000 Z=0.50000000
>           MULT= 1          ISPLIT= 5
> Zn4        NPT=  781  R0=0.00005000 RMT=    2.4900   Z: 30.0
> LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
>                      0.0000000 1.0000000 0.0000000
>                      0.0000000 0.0000000 1.0000000
> ATOM   7: X=0.50000000 Y=0.50000000 Z=0.00000000
>           MULT= 1          ISPLIT= 5
> Zn5        NPT=  781  R0=0.00005000 RMT=    2.4900   Z: 30.0
> LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
>                      0.0000000 1.0000000 0.0000000
>                      0.0000000 0.0000000 1.0000000
> ATOM   8: X=0.75000000 Y=0.00000000 Z=0.12500000
>           MULT= 4          ISPLIT= 5
>        8: X=0.25000000 Y=0.00000000 Z=0.12500000
>        8: X=0.00000000 Y=0.25000000 Z=0.87500000
>        8: X=0.00000000 Y=0.75000000 Z=0.87500000
> S 1        NPT=  781  R0=0.00010000 RMT=    2.2100   Z: 16.0
> LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
>                      0.0000000 1.0000000 0.0000000
>                      0.0000000 0.0000000 1.0000000
> ATOM   9: X=0.25000000 Y=0.50000000 Z=0.62500000
>           MULT= 4          ISPLIT= 5
>        9: X=0.75000000 Y=0.50000000 Z=0.62500000
>        9: X=0.50000000 Y=0.75000000 Z=0.37500000
>        9: X=0.50000000 Y=0.25000000 Z=0.37500000
> S 2        NPT=  781  R0=0.00010000 RMT=    2.2100   Z: 16.0
> LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
>                      0.0000000 1.0000000 0.0000000
>                      0.0000000 0.0000000 1.0000000
> ATOM  10: X=0.50000000 Y=0.25000000 Z=0.87500000
>           MULT= 4          ISPLIT= 5
>       10: X=0.50000000 Y=0.75000000 Z=0.87500000
>       10: X=0.25000000 Y=0.50000000 Z=0.12500000
>       10: X=0.75000000 Y=0.50000000 Z=0.12500000
> S 3        NPT=  781  R0=0.00010000 RMT=    2.2100   Z: 16.0
> LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
>                      0.0000000 1.0000000 0.0000000
>                      0.0000000 0.0000000 1.0000000
> ATOM  11: X=0.00000000 Y=0.75000000 Z=0.37500000
>           MULT= 4          ISPLIT= 5
>       11: X=0.00000000 Y=0.25000000 Z=0.37500000
>       11: X=0.75000000 Y=0.00000000 Z=0.62500000
>       11: X=0.25000000 Y=0.00000000 Z=0.62500000
> S 4        NPT=  781  R0=0.00010000 RMT=    2.2100   Z: 16.0
> LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
>                      0.0000000 1.0000000 0.0000000
>                      0.0000000 0.0000000 1.0000000
>    8      NUMBER OF SYMMETRY OPERATIONS
>  1 0 0 0.0000000
>  0 1 0 0.0000000
>  0 0 1 0.0000000
>        1
> -1 0 0 0.0000000
>  0-1 0 0.0000000
>  0 0 1 0.0000000
>        2
>  0 1 0 0.0000000
> -1 0 0 0.0000000
>  0 0-1 0.0000000
>        3
>  0-1 0 0.0000000
>  1 0 0 0.0000000
>  0 0-1 0.0000000
>        4
>  1 0 0 0.0000000
>  0-1 0 0.0000000
>  0 0 1 0.0000000
>        5
> -1 0 0 0.0000000
>  0 1 0 0.0000000
>  0 0 1 0.0000000
>        6
>  0 1 0 0.0000000
>  1 0 0 0.0000000
>  0 0-1 0.0000000
>        7
>  0-1 0 0.0000000
> -1 0 0 0.0000000
>  0 0-1 0.0000000
>        8
> 
> 
> .struct_supergroup
> 
> test3                                                       
> B   LATTICE,NONEQUIV.ATOMS:  6 119 I-4m2
> MODE OF CALC=RELA unit=bohr
>  15.119510 15.119510 22.676714 90.000000 90.000000 90.000000
> ATOM   1: X=0.00000000 Y=0.00000000 Z=0.00000000
>           MULT= 1          ISPLIT= 5
> Cu1        NPT=  781  R0=0.00005000 RMT=    2.4900   Z: 29.0
> LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
>                      0.0000000 1.0000000 0.0000000
>                      0.0000000 0.0000000 1.0000000
> ATOM   2: X=0.25000000 Y=0.25000000 Z=0.75000000
>           MULT= 4          ISPLIT= 5
>        2: X=0.75000000 Y=0.75000000 Z=0.75000000
>        2: X=0.25000000 Y=0.75000000 Z=0.25000000
>        2: X=0.75000000 Y=0.25000000 Z=0.25000000
> Zn1        NPT=  781  R0=0.00005000 RMT=    2.4900   Z: 30.0
> LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
>                      0.0000000 1.0000000 0.0000000
>                      0.0000000 0.0000000 1.0000000
> ATOM   3: X=0.50000000 Y=0.00000000 Z=0.00000000
>           MULT= 2          ISPLIT= 5
>        3: X=0.00000000 Y=0.50000000 Z=0.00000000
> Zn2        NPT=  781  R0=0.00005000 RMT=    2.4900   Z: 30.0
> LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
>                      0.0000000 1.0000000 0.0000000
>                      0.0000000 0.0000000 1.0000000
> ATOM   4: X=0.00000000 Y=0.00000000 Z=0.50000000
>           MULT= 1          ISPLIT= 5
> Zn3        NPT=  781  R0=0.00005000 RMT=    2.4900   Z: 30.0
> LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
>                      0.0000000 1.0000000 0.0000000
>                      0.0000000 0.0000000 1.0000000
> ATOM   5: X=0.75000000 Y=0.00000000 Z=0.12500000
>           MULT= 4          ISPLIT= 5
>        5: X=0.25000000 Y=0.00000000 Z=0.12500000
>        5: X=0.00000000 Y=0.25000000 Z=0.87500000
>        5: X=0.00000000 Y=0.75000000 Z=0.87500000
> S 1        NPT=  781  R0=0.00010000 RMT=    2.2100   Z: 16.0
> LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
>                      0.0000000 1.0000000 0.0000000
>                      0.0000000 0.0000000 1.0000000
> ATOM   6: X=0.50000000 Y=0.25000000 Z=0.87500000
>           MULT= 4          ISPLIT= 5
>        6: X=0.50000000 Y=0.75000000 Z=0.87500000
>        6: X=0.25000000 Y=0.50000000 Z=0.12500000
>        6: X=0.75000000 Y=0.50000000 Z=0.12500000
> S 2        NPT=  781  R0=0.00010000 RMT=    2.2100   Z: 16.0
> LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
>                      0.0000000 1.0000000 0.0000000
>                      0.0000000 0.0000000 1.0000000
>    8      NUMBER OF SYMMETRY OPERATIONS
>  1 0 0 0.0000000
>  0 1 0 0.0000000
>  0 0 1 0.0000000
>        1
> -1 0 0 0.0000000
>  0-1 0 0.0000000
>  0 0 1 0.0000000
>        2
>  0 1 0 0.0000000
> -1 0 0 0.0000000
>  0 0-1 0.0000000
>        3
>  0-1 0 0.0000000
>  1 0 0 0.0000000
>  0 0-1 0.0000000
>        4
>  1 0 0 0.0000000
>  0-1 0 0.0000000
>  0 0 1 0.0000000
>        5
> -1 0 0 0.0000000
>  0 1 0 0.0000000
>  0 0 1 0.0000000
>        6
>  0 1 0 0.0000000
>  1 0 0 0.0000000
>  0 0-1 0.0000000
>        7
>  0-1 0 0.0000000
> -1 0 0 0.0000000
>  0 0-1 0.0000000
>        8
> 
> .inclmcopy_st.
> 
>    6                                              NUMBER of ATOMS to CHANGE
>    1   2                                          INTERCHANGE these ATOMS
>   1.00000000000  0.00000000000  0.00000000000    1    0    0 0.00000000     SYMMETRY OPERATION
>   0.00000000000  1.00000000000  0.00000000000    0    1    0 0.00000000
>   0.00000000000  0.00000000000  1.00000000000    0    0    1 0.00000000
>    0                                              NUMBER of LM to CHANGE SIGN
>    3   3                                          INTERCHANGE these ATOMS
>   0.00000000000 -1.00000000000  0.00000000000    0   -1    0 0.00000000     SYMMETRY OPERATION
>  -1.00000000000  0.00000000000  0.00000000000   -1    0    0 0.00000000
>   0.00000000000  0.00000000000 -1.00000000000    0    0   -1 0.00000000
>   36                                              NUMBER of LM to CHANGE SIGN
>   1 0    1 0 -1.00
>   1 1   -1 1 -1.00
>  -1 1    1 1 -1.00
>   2 1   -2 1  1.00
>  -2 1    2 1  1.00
>   2 2    2 2 -1.00
>   3 0    3 0 -1.00
>   3 1   -3 1 -1.00
>  -3 1    3 1 -1.00
>  -3 2   -3 2 -1.00
>   3 3   -3 3  1.00
>  -3 3    3 3  1.00
>   4 1   -4 1  1.00
>  -4 1    4 1  1.00
>   4 2    4 2 -1.00
>   4 3   -4 3 -1.00
>  -4 3    4 3 -1.00
>  -4 4   -4 4 -1.00
>   5 0    5 0 -1.00
>   5 1   -5 1 -1.00
>  -5 1    5 1 -1.00
>  -5 2   -5 2 -1.00
>   5 3   -5 3  1.00
>  -5 3    5 3  1.00
>   5 4    5 4 -1.00
>   5 5   -5 5 -1.00
>  -5 5    5 5 -1.00
>   6 1   -6 1  1.00
>  -6 1    6 1  1.00
>   6 2    6 2 -1.00
>   6 3   -6 3 -1.00
>  -6 3    6 3 -1.00
>  -6 4   -6 4 -1.00
>   6 5   -6 5  1.00
>  -6 5    6 5  1.00
>   6 6    6 6 -1.00
>    4   5                                          INTERCHANGE these ATOMS
>   1.00000000000  0.00000000000  0.00000000000    1    0    0 0.00000000     SYMMETRY OPERATION
>   0.00000000000  1.00000000000  0.00000000000    0    1    0 0.00000000
>   0.00000000000  0.00000000000  1.00000000000    0    0    1 0.00000000
>    0                                              NUMBER of LM to CHANGE SIGN
>    6   7                                          INTERCHANGE these ATOMS
>   1.00000000000  0.00000000000  0.00000000000    1    0    0 0.00000000     SYMMETRY OPERATION
>   0.00000000000  1.00000000000  0.00000000000    0    1    0 0.00000000
>   0.00000000000  0.00000000000  1.00000000000    0    0    1 0.00000000
>    0                                              NUMBER of LM to CHANGE SIGN
>    8   9                                          INTERCHANGE these ATOMS
>   1.00000000000  0.00000000000  0.00000000000    1    0    0 0.00000000     SYMMETRY OPERATION
>   0.00000000000  1.00000000000  0.00000000000    0    1    0 0.00000000
>   0.00000000000  0.00000000000  1.00000000000    0    0    1 0.00000000
>    0                                              NUMBER of LM to CHANGE SIGN
>   10  11                                          INTERCHANGE these ATOMS
>   1.00000000000  0.00000000000  0.00000000000    1    0    0 0.00000000     SYMMETRY OPERATION
>   0.00000000000  1.00000000000  0.00000000000    0    1    0 0.00000000
>   0.00000000000  0.00000000000  1.00000000000    0    0    1 0.00000000
>    0                                              NUMBER of LM to CHANGE SIGN
>    1   0   0   0.50000
>    0   1   0   0.50000
>    0   0   1   0.50000
>  The symmetry operation above is one of the operations of the NM-supergroup
>  missing in the AFM-subgroup (transfers spin-up into spin-dn atom)
> 
> 
> 
> 
> 
> 
> 
> 
> 
> 
> 
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-- 

                                       P.Blaha
--------------------------------------------------------------------------
Peter BLAHA, Inst.f. Materials Chemistry, TU Vienna, A-1060 Vienna
Phone: +43-1-58801-15671             FAX: +43-1-58801-15698
Email: blaha at theochem.tuwien.ac.at    WWW: http://info.tuwien.ac.at/theochem/
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