[Wien] L2main - QTL-B Error

Shahid rasul srjurir at gmail.com
Tue Aug 4 12:47:27 CEST 2009


Dear Dr Blaha and users

I have the same problem again and again. I have tried once more with
creating new session and structure files. Please have a look at case.in1 and
case.scf2 files and suggest accordingly. Thanks a lot.
P.S: s and p states have different energies this time.
regards,
SHAHID RASUL
Doctoral Student
Department of Materials Engineering
Mob:+81-80-3435-1632
Ogden Nash <http://www.brainyquote.com/quotes/authors/o/ogden_nash.html>  -
"The trouble with a kitten is that when it grows up, it's always a cat."

On Tue, Jul 28, 2009 at 7:07 PM, Shahid rasul <srjurir at gmail.com> wrote:

> Dear Dr. Blah
> Thanks for your reply. I changed it myself with out any clue. However, even
> it was not changed the generated error was the same.
>
> SHAHID RASUL
>
>
> On Tue, Jul 28, 2009 at 5:42 PM, Peter Blaha <pblaha at theochem.tuwien.ac.at
> > wrote:
>
>> How was the case.in1 file produced ? Did you change anything yourself ??
>>
>>  0.30    4  0      (GLOBAL E-PARAMETER WITH n OTHER CHOICES, global
>> APW/LAPW)
>>  1    0.30      0.000 CONT 1
>>  1   -6.11      0.005 STOP 1
>>  0   -6.11      0.010 CONT 1
>>  0    0.30      0.000 CONT 1
>>
>> It is very unusual that s and p states have the same energy-parameter
>> (-6.11) ???
>>
>> Shahid rasul schrieb:
>>
>>> Dear Users
>>>
>>> I am using Wien2k for calculation of electronic structure of LiFePO4.
>>> When i start the cycle it stops and gives the following error.
>>>
>>> *L2main - QTL-B Error
>>>
>>>
>>> 129.024u 3.886s 0:17.86 744.1%  0+0k 0+6872io 0pf+0w*
>>>
>>> I have checked the Scf file and it shows the following error:
>>>
>>> QTL-B VALUE .EQ. 8390.54042   in Band of energy   -6.11181   ATOM=    3
>>> L=  0
>>>    Check for ghostbands or EIGENVALUES BELOW XX messages
>>>    Adjust your Energy-parameters or use -in1new switch, check RMTs  !!!
>>>
>>>
>>> :WARN : QTL-B value eq.8390.54  in Band of energy  -6.11181   ATOM=    3
>>>   L=  0
>>> :WARN : You should change the E-parameter in case.in1 or use -in1new
>>> switch
>>>
>>> I have tried the FAQS and the manual to get rid of the error but could
>>> not. Could you please help me out there. Please also find the structure.in1
>>> file as well. Thanks a lot.
>>>
>>> SHAHID RASUL
>>>
>>>
>>> ------------------------------------------------------------------------
>>>
>>> _______________________________________________
>>> Wien mailing list
>>> Wien at zeus.theochem.tuwien.ac.at
>>> http://zeus.theochem.tuwien.ac.at/mailman/listinfo/wien
>>>
>>
>> --
>>
>>                                      P.Blaha
>> --------------------------------------------------------------------------
>> Peter BLAHA, Inst.f. Materials Chemistry, TU Vienna, A-1060 Vienna
>> Phone: +43-1-58801-15671             FAX: +43-1-58801-15698
>> Email: blaha at theochem.tuwien.ac.at    WWW:
>> http://info.tuwien.ac.at/theochem/
>> --------------------------------------------------------------------------
>> _______________________________________________
>> Wien mailing list
>> Wien at zeus.theochem.tuwien.ac.at
>> http://zeus.theochem.tuwien.ac.at/mailman/listinfo/wien
>>
>
>
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:GMA  : POTENTIAL AND CHARGE CUT-OFF  12.00 Ry**.5
         Bandranges (emin - emax) and occupancy:
:BAN00099:  99    0.017191    0.037359  2.00000000
:BAN00100: 100    0.019009    0.047024  2.00000000
:BAN00101: 101    0.471543    0.479463  2.00000000
:BAN00102: 102    0.472298    0.479473  2.00000000
:BAN00103: 103    0.475473    0.483813  2.00000000
:BAN00104: 104    0.475909    0.483813  2.00000000
:BAN00105: 105    0.479328    0.488531  2.00000000
:BAN00106: 106    0.481627    0.488531  2.00000000
:BAN00107: 107    0.483778    0.492756  2.00000000
:BAN00108: 108    0.483960    0.494241  1.88444665
:BAN00109: 109    0.491342    0.499685  0.11555335
:BAN00110: 110    0.492974    0.499772  0.00000000
:BAN00111: 111    0.494457    0.502726  0.00000000
:BAN00112: 112    0.495395    0.503082  0.00000000
:BAN00113: 113    0.531525    0.541478  0.00000000
:BAN00114: 114    0.532065    0.541606  0.00000000
        Energy to separate low and high energystates:   -0.21961


:NOE  : NUMBER OF ELECTRONS          = 216.000

:FER  : F E R M I - ENERGY(TETRAH.M.)=   0.49279




:POS001: AT.NR.  -1 POSITION = 0.50000 0.00000 0.50000  MULTIPLICITY =  4

       LMMAX 28
       LM=   0 0  2 0  2 1 -2 1  2 2 -2 2  4 0  4 1 -4 1  4 2 -4 2  4 3 -4 3  4 4 -4 4  6 0  6 1
        -6 1  6 2 -6 2  6 3 -6 3  6 4 -6 4  6 5 -6 5  6 6 -6 6

:CHA001: TOTAL CHARGE INSIDE SPHERE   1 =     2.201053
:PCS001: PARTIAL CHARGES SPHERE =  1 S,P,D,F,PX,PY,PZ,D-Z2,D-X2Y2,D-XY,D-XZ,D-YZ 
:QTL001: 2.0443 0.1129 0.0328 0.0084 0.0308 0.0405 0.0415 0.0026 0.0057 0.0045 0.0081 0.0120
        Q-s-low E-s-low   Q-p-low E-p-low   Q-d-low E-d-low   Q-f-low E-f-low
:EPL001:  2.0053 -2.9006    0.0337 -0.5626    0.0102 -0.6363    0.0027 -0.6837
        Q-s-hi  E-s-hi    Q-p-hi  E-p-hi    Q-d-hi  E-d-hi    Q-f-hi  E-f-hi 
:EPH001:  0.0391 -0.1082    0.0792 -0.0623    0.0226 -0.0263    0.0058 -0.0307

                      QXX         QXY         QYY         QZZ       UP TO R

:VZZ001:             0.08146    -0.05533    -0.03720    -0.04426       1.960




:POS002: AT.NR.  -2 POSITION = 0.78200 0.25000 0.52600  MULTIPLICITY =  4

       LMMAX 28
       LM=   0 0  1 1 -1 1  2 0  2 2 -2 2  3 1 -3 1  3 3 -3 3  4 0  4 2 -4 2  4 4 -4 4  5 1 -5 1
         5 3 -5 3  5 5 -5 5  6 0  6 2 -6 2  6 4 -6 4  6 6 -6 6

:CHA002: TOTAL CHARGE INSIDE SPHERE   2 =    11.875910
:PCS002: PARTIAL CHARGES SPHERE =  2 S,P,D,F,PX,PY,PZ,D-Z2,D-X2Y2,D-XY,D-XZ,D-YZ 
:QTL002: 2.0897 6.0606 3.7049 0.0159 2.0138 2.0206 2.0262 0.4325 1.2723 0.5335 0.4567 1.0100
        Q-s-low E-s-low   Q-p-low E-p-low   Q-d-low E-d-low   Q-f-low E-f-low
:EPL002:  2.0414 -5.7037    5.9968 -3.3165    0.0743 -0.4195    0.0058 -0.5764
        Q-s-hi  E-s-hi    Q-p-hi  E-p-hi    Q-d-hi  E-d-hi    Q-f-hi  E-f-hi 
:EPH002:  0.0483 -0.0773    0.0638 -0.0625    3.6306  0.4480    0.0101 -0.0392

                      QXX         QXY         QYY         QZZ       UP TO R

:VZZ002:            -1.22249    12.39061   -15.50975    16.73224       2.050




:POS003: AT.NR.  -3 POSITION = 0.59400 0.25000 0.08300  MULTIPLICITY =  4

       LMMAX 28
       LM=   0 0  1 1 -1 1  2 0  2 2 -2 2  3 1 -3 1  3 3 -3 3  4 0  4 2 -4 2  4 4 -4 4  5 1 -5 1
         5 3 -5 3  5 5 -5 5  6 0  6 2 -6 2  6 4 -6 4  6 6 -6 6

:CHA003: TOTAL CHARGE INSIDE SPHERE   3 =     8.964506
:PCS003: PARTIAL CHARGES SPHERE =  3 S,P,D,F,PX,PY,PZ,D-Z2,D-X2Y2,D-XY,D-XZ,D-YZ 
:QTL003: 2.3475 6.4301 0.1690 0.0149 2.1488 2.1430 2.1383 0.0333 0.0413 0.0306 0.0301 0.0335
        Q-s-low E-s-low   Q-p-low E-p-low   Q-d-low E-d-low   Q-f-low E-f-low
:EPL003:  0.3397 -0.8102    6.3997 -7.8024    0.0451 -0.9624    0.0049 -1.1111
        Q-s-hi  E-s-hi    Q-p-hi  E-p-hi    Q-d-hi  E-d-hi    Q-f-hi  E-f-hi 
:EPH003:  2.0078 -0.0577    0.0304 -0.0289    0.1238 -0.0853    0.0100 -0.0256

                      QXX         QXY         QYY         QZZ       UP TO R

:VZZ003:            -1.24924     0.54730     0.05508     1.19416       1.430




:POS004: AT.NR.  -4 POSITION = 0.59800 0.25000 0.75600  MULTIPLICITY =  4

       LMMAX 28
       LM=   0 0  1 1 -1 1  2 0  2 2 -2 2  3 1 -3 1  3 3 -3 3  4 0  4 2 -4 2  4 4 -4 4  5 1 -5 1
         5 3 -5 3  5 5 -5 5  6 0  6 2 -6 2  6 4 -6 4  6 6 -6 6

:CHA004: TOTAL CHARGE INSIDE SPHERE   4 =     5.104139
:PCS004: PARTIAL CHARGES SPHERE =  4 S,P,D,F,PX,PY,PZ,D-Z2,D-X2Y2,D-XY,D-XZ,D-YZ 
:QTL004: 1.4666 3.6237 0.0118 0.0017 1.1529 1.2201 1.2507 0.0018 0.0058 0.0017 0.0020 0.0005
        Q-s-low E-s-low   Q-p-low E-p-low   Q-d-low E-d-low   Q-f-low E-f-low
:EPL004:  1.4536 -1.1862    0.9721 -0.3485    0.0071 -0.7773    0.0010 -1.2010
        Q-s-hi  E-s-hi    Q-p-hi  E-p-hi    Q-d-hi  E-d-hi    Q-f-hi  E-f-hi 
:EPH004:  0.0131 -0.0504    2.6517 -0.0512    0.0047  0.0942    0.0007 -0.0053

                      QXX         QXY         QYY         QZZ       UP TO R

:VZZ004:             6.66720    -1.66599    -1.77200    -4.89519       1.430




:POS005: AT.NR.  -5 POSITION = 0.95700 0.25000 0.29400  MULTIPLICITY =  4

       LMMAX 28
       LM=   0 0  1 1 -1 1  2 0  2 2 -2 2  3 1 -3 1  3 3 -3 3  4 0  4 2 -4 2  4 4 -4 4  5 1 -5 1
         5 3 -5 3  5 5 -5 5  6 0  6 2 -6 2  6 4 -6 4  6 6 -6 6

:CHA005: TOTAL CHARGE INSIDE SPHERE   5 =     5.129888
:PCS005: PARTIAL CHARGES SPHERE =  5 S,P,D,F,PX,PY,PZ,D-Z2,D-X2Y2,D-XY,D-XZ,D-YZ 
:QTL005: 1.4697 3.6439 0.0143 0.0017 1.2228 1.1652 1.2560 0.0019 0.0044 0.0044 0.0003 0.0031
        Q-s-low E-s-low   Q-p-low E-p-low   Q-d-low E-d-low   Q-f-low E-f-low
:EPL005:  1.4610 -1.2083    1.2073 -0.3415    0.0090 -0.7066    0.0011 -1.1662
        Q-s-hi  E-s-hi    Q-p-hi  E-p-hi    Q-d-hi  E-d-hi    Q-f-hi  E-f-hi 
:EPH005:  0.0086 -0.0644    2.4366 -0.0680    0.0052  0.1272    0.0006  0.0319

                      QXX         QXY         QYY         QZZ       UP TO R

:VZZ005:            -1.10396     1.92078     5.88369    -4.77973       1.430




:POS006: AT.NR.  -6 POSITION = 0.66600 0.04700 0.21500  MULTIPLICITY =  8

       LMMAX 49
       LM=   0 0  1 0  1 1 -1 1  2 0  2 1 -2 1  2 2 -2 2  3 0  3 1 -3 1  3 2 -3 2  3 3 -3 3  4 0
         4 1 -4 1  4 2 -4 2  4 3 -4 3  4 4 -4 4  5 0  5 1 -5 1  5 2 -5 2  5 3 -5 3  5 4 -5 4  5 5

        -5 5  6 0  6 1 -6 1  6 2 -6 2  6 3 -6 3  6 4 -6 4  6 5 -6 5  6 6 -6 6

:CHA006: TOTAL CHARGE INSIDE SPHERE   6 =     5.046319
:PCS006: PARTIAL CHARGES SPHERE =  6 S,P,D,F,PX,PY,PZ,D-Z2,D-X2Y2,D-XY,D-XZ,D-YZ 
:QTL006: 1.4629 3.5680 0.0136 0.0016 1.2074 1.1607 1.1999 0.0017 0.0024 0.0044 0.0013 0.0037
        Q-s-low E-s-low   Q-p-low E-p-low   Q-d-low E-d-low   Q-f-low E-f-low
:EPL006:  1.4520 -1.1721    0.9681 -0.3361    0.0074 -0.7042    0.0009 -1.0942
        Q-s-hi  E-s-hi    Q-p-hi  E-p-hi    Q-d-hi  E-d-hi    Q-f-hi  E-f-hi 
:EPH006:  0.0108 -0.0419    2.5998 -0.0472    0.0061  0.1755    0.0007  0.0348

                      QXX         QXY         QYY         QZZ       UP TO R

:VZZ006:            -2.05764    -3.62025     3.41499    -1.35735       1.430

:CHA  : TOTAL CHARGE INSIDE UNIT CELL =     216.000000

:SUM  : SUM OF EIGENVALUES =        -396.312442579



   QTL-B VALUE .EQ. **********   in Band of energy   -0.05857   ATOM=    3   L=  0
    Check for ghostbands or EIGENVALUES BELOW XX messages
    Adjust your Energy-parameters or use -in1new switch, check RMTs  !!!


:WARN : QTL-B value eq.*******  in Band of energy  -0.05857   ATOM=    3   L=  0
:WARN : You should change the E-parameter in case.in1 or use -in1new switch
-------------- next part --------------
WFFIL        (WFPRI, SUPWF)
  7.00       10    4 (R-MT*K-MAX; MAX L IN WF, V-NMT
  0.30    2  0      (GLOBAL E-PARAMETER WITH n OTHER CHOICES, global APW/LAPW)
 0    0.30      0.000 CONT 1
 0   -3.50      0.005 STOP 1
  0.30    5  0      (GLOBAL E-PARAMETER WITH n OTHER CHOICES, global APW/LAPW)
 0    0.30      0.000 CONT 1
 0   -6.50      0.005 STOP 1
 1    0.30      0.000 CONT 1
 1   -3.97      0.005 STOP 1
 2    0.30      0.010 CONT 1
  0.30    4  0      (GLOBAL E-PARAMETER WITH n OTHER CHOICES, global APW/LAPW)
 1    0.30      0.000 CONT 1
 1   -8.80      0.005 STOP 1
 0   -0.79      0.010 CONT 1
 0    0.30      0.000 CONT 1
  0.30    3  0      (GLOBAL E-PARAMETER WITH n OTHER CHOICES, global APW/LAPW)
 0   -1.55      0.010 CONT 1
 0    0.30      0.000 CONT 1
 1    0.30      0.000 CONT 1
  0.30    3  0      (GLOBAL E-PARAMETER WITH n OTHER CHOICES, global APW/LAPW)
 0   -1.55      0.010 CONT 1
 0    0.30      0.000 CONT 1
 1    0.30      0.000 CONT 1
  0.30    3  0      (GLOBAL E-PARAMETER WITH n OTHER CHOICES, global APW/LAPW)
 0   -1.55      0.010 CONT 1
 0    0.30      0.000 CONT 1
 1    0.30      0.000 CONT 1
K-VECTORS FROM UNIT:4  -13.0       2.0   126   emin/emax/nband #red


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