[Wien] The magnetic structure for zinc blende non magnetic structure

Abderrahmane Reggad jazairdz at gmail.com
Fri Oct 13 08:35:52 CEST 2017


Sorry the link is

http://wien2k-algerien1970.blogspot.com/2016/06/structural-and-magnetic-properties-of.html

2017-10-13 8:11 GMT+02:00 Abderrahmane Reggad <jazairdz at gmail.com>:

> Dear Delamora
>
> It's up to now that I start to work with the magnetic structure of the
> zinc blende one.
>
>
> - The zinc blende structure for NiS has not been studied before and I am
> studing the possibility of its existence.
>
> - In the literature, I found that the magnetic ground phase of the zinc
> blende is of type III unlike the one of the NaCl which is of type II.
>
> - I have tried to construct the magnetic structure of the zinc blende
> structure according to this link and I want to know if I am true or not.
>
> http://wien2k-algerien1970.blogspot.com/search/label/
> Magnetic%20structures?updated-max=2016-06-27T02:29:00%2B01:
> 00&max-results=20&start=33&by-date=false
>
> My procedure is as follows:
>
> supercell 1x1x2  P
>
> NiS-ZB-afmIII
>
> P   LATTICE,NONEQUIV. ATOMS 16
> MODE OF CALC=RELA unit=ang
>   9.524223  9.524223 19.048446 90.000000 90.000000 90.000000
> ATOM   1: X=0.00000000 Y=0.00000000 Z=0.00000000
>           MULT= 1          ISPLIT= 8
> Ni         NPT=  781  R0=0.00005000 RMT=    2.2500   Z: 28.0
> LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
>                      0.0000000 1.0000000 0.0000000
>                      0.0000000 0.0000000 1.0000000
> ATOM   2: X=0.00000000 Y=0.00000000 Z=0.50000000
>           MULT= 1          ISPLIT= 8
> Ni         NPT=  781  R0=0.00005000 RMT=    2.2500   Z: 28.0
> LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
>                      0.0000000 1.0000000 0.0000000
>                      0.0000000 0.0000000 1.0000000
> ATOM   3: X=0.50000000 Y=0.50000000 Z=0.00000000
>           MULT= 1          ISPLIT= 8
> Ni         NPT=  781  R0=0.00005000 RMT=    2.2500   Z: 28.0
> LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
>                      0.0000000 1.0000000 0.0000000
>                      0.0000000 0.0000000 1.0000000
> ATOM   4: X=0.50000000 Y=0.50000000 Z=0.50000000
>           MULT= 1          ISPLIT= 8
> Ni         NPT=  781  R0=0.00005000 RMT=    2.2500   Z: 28.0
> LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
>                      0.0000000 1.0000000 0.0000000
>                      0.0000000 0.0000000 1.0000000
> ATOM   5: X=0.50000000 Y=0.00000000 Z=0.25000000
>           MULT= 1          ISPLIT= 8
> Ni         NPT=  781  R0=0.00005000 RMT=    2.2500   Z: 28.0
> LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
>                      0.0000000 1.0000000 0.0000000
>                      0.0000000 0.0000000 1.0000000
> ATOM   6: X=0.50000000 Y=0.00000000 Z=0.75000000
>           MULT= 1          ISPLIT= 8
> Ni         NPT=  781  R0=0.00005000 RMT=    2.2500   Z: 28.0
> LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
>                      0.0000000 1.0000000 0.0000000
>                      0.0000000 0.0000000 1.0000000
> ATOM   7: X=0.00000000 Y=0.50000000 Z=0.25000000
>           MULT= 1          ISPLIT= 8
> Ni         NPT=  781  R0=0.00005000 RMT=    2.2500   Z: 28.0
> LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
>                      0.0000000 1.0000000 0.0000000
>                      0.0000000 0.0000000 1.0000000
> ATOM   8: X=0.00000000 Y=0.50000000 Z=0.75000000
>           MULT= 1          ISPLIT= 8
> Ni         NPT=  781  R0=0.00005000 RMT=    2.2500   Z: 28.0
> LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
>                      0.0000000 1.0000000 0.0000000
>                      0.0000000 0.0000000 1.0000000
> ATOM   9: X=0.25000000 Y=0.25000000 Z=0.12500000
>           MULT= 1          ISPLIT= 8
> S          NPT=  781  R0=0.00010000 RMT=    1.8400   Z: 16.0
> LOCAL ROT MATRIX:    0.0000000 0.0000000 0.0000000
>                      0.0000000 0.0000000 0.0000000
>                      0.0000000 0.0000000 0.0000000
> ATOM  10: X=0.25000000 Y=0.25000000 Z=0.62500000
>           MULT= 1          ISPLIT= 8
> S          NPT=  781  R0=0.00010000 RMT=    1.8400   Z: 16.0
> LOCAL ROT MATRIX:    0.0000000 0.0000000 0.0000000
>                      0.0000000 0.0000000 0.0000000
>                      0.0000000 0.0000000 0.0000000
> ATOM  11: X=0.75000000 Y=0.75000000 Z=0.12500000
>           MULT= 1          ISPLIT= 8
> S          NPT=  781  R0=0.00010000 RMT=    1.8400   Z: 16.0
> LOCAL ROT MATRIX:    0.0000000 0.0000000 0.0000000
>                      0.0000000 0.0000000 0.0000000
>                      0.0000000 0.0000000 0.0000000
> ATOM  12: X=0.75000000 Y=0.75000000 Z=0.62500000
>           MULT= 1          ISPLIT= 8
> S          NPT=  781  R0=0.00010000 RMT=    1.8400   Z: 16.0
> LOCAL ROT MATRIX:    0.0000000 0.0000000 0.0000000
>                      0.0000000 0.0000000 0.0000000
>                      0.0000000 0.0000000 0.0000000
> ATOM  13: X=0.75000000 Y=0.25000000 Z=0.37500000
>           MULT= 1          ISPLIT= 8
> S          NPT=  781  R0=0.00010000 RMT=    1.8400   Z: 16.0
> LOCAL ROT MATRIX:    0.0000000 0.0000000 0.0000000
>                      0.0000000 0.0000000 0.0000000
>                      0.0000000 0.0000000 0.0000000
> ATOM  14: X=0.75000000 Y=0.25000000 Z=0.87500000
>           MULT= 1          ISPLIT= 8
> S          NPT=  781  R0=0.00010000 RMT=    1.8400   Z: 16.0
> LOCAL ROT MATRIX:    0.0000000 0.0000000 0.0000000
>                      0.0000000 0.0000000 0.0000000
>                      0.0000000 0.0000000 0.0000000
> ATOM  15: X=0.25000000 Y=0.75000000 Z=0.37500000
>           MULT= 1          ISPLIT= 8
> S          NPT=  781  R0=0.00010000 RMT=    1.8400   Z: 16.0
> LOCAL ROT MATRIX:    0.0000000 0.0000000 0.0000000
>                      0.0000000 0.0000000 0.0000000
>                      0.0000000 0.0000000 0.0000000
> ATOM  16: X=0.25000000 Y=0.75000000 Z=0.87500000
>           MULT= 1          ISPLIT= 8
> S          NPT=  781  R0=0.00010000 RMT=    1.8400   Z: 16.0
> LOCAL ROT MATRIX:    0.0000000 0.0000000 0.0000000
>                      0.0000000 0.0000000 0.0000000
>                      0.0000000 0.0000000 0.0000000
>    0      NUMBER OF SYMMETRY OPERATIONS
>
>
> atom1 ----> 1
> atom2----->2
> atom3----->2
> atom4----->1
> atom5----->1
> atom6----->2
> atom7----->2
> atom8----->1
>
> with sgroup I got
>
> NiS-ZB-afmIII
> B   LATTICE,NONEQUIV.ATOMS:  3 122 I-42d
> MODE OF CALC=RELA unit=ang
>   9.524223  9.524223 19.048446 90.000000 90.000000 90.000000
> ATOM   1: X=0.00000000 Y=0.50000000 Z=0.25000000
>           MULT= 2          ISPLIT= 8
>        1: X=0.50000000 Y=0.50000000 Z=0.50000000
> Ni1        NPT=  781  R0=0.00005000 RMT= 2.03        Z: 28.0
> LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
>                      0.0000000 1.0000000 0.0000000
>                      0.0000000 0.0000000 1.0000000
> ATOM   2: X=0.50000000 Y=0.00000000 Z=0.25000000
>           MULT= 2          ISPLIT= 8
>        2: X=0.00000000 Y=0.00000000 Z=0.50000000
> Ni2        NPT=  781  R0=0.00005000 RMT= 2.03        Z: 28.0
> LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
>                      0.0000000 1.0000000 0.0000000
>                      0.0000000 0.0000000 1.0000000
> ATOM   3: X=0.75000000 Y=0.25000000 Z=0.62500000
>           MULT= 4          ISPLIT= 8
>        3: X=0.25000000 Y=0.75000000 Z=0.62500000
>        3: X=0.25000000 Y=0.25000000 Z=0.37500000
>        3: X=0.75000000 Y=0.75000000 Z=0.37500000
> S 1        NPT=  781  R0=0.00010000 RMT= 1.66        Z: 16.0
> LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
>                      0.0000000 1.0000000 0.0000000
>                      0.0000000 0.0000000 1.0000000
>    8      NUMBER OF SYMMETRY OPERATIONS
>
>
> I want to know if it's true or not
>
> Best regards
>
>
>
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