[Wien] Optic program error for XMCD calculation of Fe3O4

Jose Maria Castillo chema30080 at gmail.com
Wed Jun 27 14:40:19 CEST 2018


Yes, I tried with bcc-Fe and I didn't have any problem.

Best regards,

José María Castillo Robles
El mié., 27 de jun. de 2018 a la(s) 03:34, Peter Blaha
(pblaha at theochem.tuwien.ac.at) escribió:
>
> Did you try bccFe ?? This runs for me (and I would like to get a hint if
> the problem comes from more atoms/cell or if your optics is not updated
> properly)
>
> On 06/27/2018 08:07 AM, Jose Maria Castillo wrote:
> > Dear Prof. Blaha,
> >
> > Thank you for your answer.  Yes, I used the patch that is in the following post:
> >
> > https://www.mail-archive.com/wien@zeus.theochem.tuwien.ac.at/msg17555.html
> >
> > but I got the error that I mentioned.
> >
> > Best regards,
> >
> > José María Castillo Robles
> >
> > El mié., 27 de jun. de 2018 a la(s) 00:26, Peter Blaha
> > (pblaha at theochem.tuwien.ac.at) escribió:
> >>
> >> Did you search the mailinglist for recent threads about xmcd ?
> >>
> >> There was a patch for a severe bug mentioned just a few weeks ago.
> >>
> >> Regards
> >>
> >> Am 27.06.2018 um 07:11 schrieb Jose Maria Castillo:
> >>> Dear Prof. Blaha and Wien2k users,
> >>>
> >>> I am using WIEN2k version WIEN2k_17.1 for calculating XMCD spectra of
> >>> Fe3O4 at the L23 edge for Fe.  First, I did a spin polarized
> >>> calculation using:
> >>>
> >>> init_lapw (using default settings)
> >>> runsp_lapw -ec 0.0001
> >>>
> >>> and then a calculation including spin orbit coupling. I ran the
> >>> following commands:
> >>>
> >>> initso_lapw (using default settings)
> >>> rm *.broyd*
> >>> runsp_lapw -so -ec 0.0001
> >>>
> >>> and I don't get any errors in the calculations. In both cases, the
> >>> Brillouin zone was sampled with 1000 k-points.
> >>>
> >>> After this, I ran the commands that are mentioned in the usersguide
> >>> (section 8.17 "OPTIC calculating optical properties") :
> >>>
> >>> 1. cp Fe3O4.struct Fe3O4.ksym
> >>> 2. x kgen -so -fbz
> >>> 3. change TOT to FERMI in Fe3O4.in2c and Fe3O4.in2
> >>> 4. put TETRA with value 101 in Fe3O4.in2c and Fe3O4.in2
> >>> 5. set IPRINT=1 in Fe3O4.inc
> >>> 6. rm *broyd*
> >>> 7. x lapw1 -up
> >>> 8. x lapw1 -dn
> >>> 9. x lapwso -up
> >>> 10. x lapw2 -fermi -up
> >>> 11. x lapw2 -fermi -dn
> >>> 12. x lcore -up
> >>> 13. x lcore -dn
> >>> 14. x optic -so -up
> >>>
> >>> Before optic program, it ran without errors, but after running optic
> >>> program it crashes with the following error:
> >>>
> >>>
> >>> user at machine:~/Fe3O4$ x optic -so -up
> >>>    emin,emax,nbvalmax  -5.00000000000000        3.00000000000000             9999
> >>>    XMCD selected for atom           2 L23
> >>>    LSO=  T
> >>> forrtl: severe (64): input conversion error, unit 18, file
> >>> /home/user/Fe3O4/Fe3O4.vspup
> >>> Image              PC                Routine            Line
> >>> Source
> >>> opticc             0000000000436D53  Unknown               Unknown  Unknown
> >>> opticc             000000000045C00A  Unknown               Unknown  Unknown
> >>> opticc             0000000000403709  atpar_                     62  atpar_op.f
> >>> opticc             0000000000429D22  cor_mat_                  345
> >>> sph-UPcor_tmp.f
> >>> opticc             00000000004112F1  MAIN__                    460  opmain.f
> >>> opticc             0000000000402BEE  Unknown               Unknown  Unknown
> >>> libc-2.23.so       00002AE5A5E03830  __libc_start_main     Unknown  Unknown
> >>> opticc             0000000000402AE9  Unknown               Unknown  Unknown
> >>> 0.0u 0.0s 0:00.01 100.0% 0+0k 0+72io 0pf+0w
> >>> error: command   /home/user/WIEN2k_ifort/opticc upoptic.def   failed
> >>>
> >>> In order to discard a problem with the structure, I tried to do the
> >>> XMCD calculation for two different solids (Fe3O4 and CeFe2)
> >>> and I got the same error. It looks like the format of Fe3O4.vspup is
> >>> not compatible with optic program.
> >>>
> >>> I would like to ask for your help. I send you the input files for the
> >>> optic program, the output, as well as the error files.
> >>>
> >>> Thanks in advance for your help.
> >>>
> >>> Best regards!
> >>> José María Castillo Robles
> >>> -------------------------Inputs--------------------------------------------
> >>> Fe3O4.inop
> >>> 99999 1       number of k-points, first k-point
> >>> -5.0 3.0 9999 Emin, Emax for matrix elements, NBvalMAX
> >>> XMCD 1 L23    xmcd  atom_num edge
> >>> 2             number of choices (columns in *outmat): 2: hex or tetrag. case
> >>> 1             Re xx
> >>> 3             Re zz
> >>> OFF           ON/OFF   writes MME to unit 4
> >>> -----------------------------------------------------------------------------------------------
> >>> Fe3O4.inc
> >>>    1 0.00  1  NUMBER OF ORBITALS (EXCLUDING SPIN)
> >>> 1,-1,2               ( N,KAPPA,OCCUP)
> >>>    5 0.00  1  NUMBER OF ORBITALS (EXCLUDING SPIN)
> >>> 1,-1,2               ( N,KAPPA,OCCUP)
> >>> 2,-1,2               ( N,KAPPA,OCCUP)
> >>> 2, 1,2               ( N,KAPPA,OCCUP)
> >>> 2,-2,4               ( N,KAPPA,OCCUP)
> >>> 3,-1,2               ( N,KAPPA,OCCUP)
> >>>    5 0.00  1  NUMBER OF ORBITALS (EXCLUDING SPIN)
> >>> 1,-1,2               ( N,KAPPA,OCCUP)
> >>> 2,-1,2               ( N,KAPPA,OCCUP)
> >>> 2, 1,2               ( N,KAPPA,OCCUP)
> >>> 2,-2,4               ( N,KAPPA,OCCUP)
> >>> 3,-1,2               ( N,KAPPA,OCCUP)
> >>>    0
> >>> -------------------------------------------------------------------------------------------------
> >>> Fe3O4.in2c and Fe3O4.in2
> >>> FERMI           (TOT,FOR,QTL,EFG,FERMI)
> >>>      -12.0   132.0   0.50 0.05  1   EMIN, NE, ESEPERMIN, ESEPER0, iqtls
> >>> TETRA    101        (GAUSS,ROOT,TEMP,TETRA,ALL      eval)
> >>>     0 0  1 1 -1 1  2 0  2 2 -2 2  3 1 -3 1  3 3 -3 3  4 0  4 2 -4 2  4 4
> >>> -4 4  5 1 -5 1  5 3 -5 3  5 5 -5 5  6 0  6 2 -6 2  6 4 -6 4  6 6 -6 6
> >>>     0 0  2 0  2 2 -2 2  4 0  4 2 -4 2  4 4 -4 4  6 0  6 2 -6 2  6 4 -6 4  6 6 -6 6
> >>>     0 0  2 0 -3 2  4 0  4 4 -5 2  6 0  6 4
> >>>    12.00          GMAX
> >>> NOFILE        FILE/NOFILE  write recprlist
> >>> ----------------------------------------------------------------------------------------------------
> >>> Fe3O4.struct
> >>> Fe3o4                                    s-o calc. M||  0.00  0.00  1.00
> >>> F                            3 227_
> >>>                RELA
> >>>    15.864257 15.864257 15.864257 90.000000 90.000000 90.000000
> >>> ATOM  -1: X=0.24450000 Y=0.24450000 Z=0.24450000
> >>>             MULT= 8          ISPLIT= 8
> >>>         -1: X=0.75550000 Y=0.75550000 Z=0.75550000
> >>>         -1: X=0.75550000 Y=0.49450000 Z=0.49450000
> >>>         -1: X=0.24450000 Y=0.00550000 Z=0.00550000
> >>>         -1: X=0.00550000 Y=0.00550000 Z=0.24450000
> >>>         -1: X=0.49450000 Y=0.49450000 Z=0.75550000
> >>>         -1: X=0.49450000 Y=0.75550000 Z=0.49450000
> >>>         -1: X=0.00550000 Y=0.24450000 Z=0.00550000
> >>> O 1        NPT=  781  R0=.000100000 RMT=   1.65000   Z:   8.00000
> >>> LOCAL ROT MATRIX:    0.0000000-0.7071068-0.7071068
> >>>                        0.0000000-0.7071068 0.7071068
> >>>                       -1.0000000 0.0000000 0.0000000
> >>> ATOM  -2: X=0.00000000 Y=0.00000000 Z=0.00000000
> >>>             MULT= 4          ISPLIT= 8
> >>>         -2: X=0.00000000 Y=0.25000000 Z=0.25000000
> >>>         -2: X=0.25000000 Y=0.25000000 Z=0.00000000
> >>>         -2: X=0.25000000 Y=0.00000000 Z=0.25000000
> >>> Fe1        NPT=  781  R0=.000050000 RMT=   1.92000   Z:  26.00000
> >>> LOCAL ROT MATRIX:    0.0000000-0.7071068-0.7071068
> >>>                        0.0000000-0.7071068 0.7071068
> >>>                       -1.0000000 0.0000000 0.0000000
> >>> ATOM  -3: X=0.37500000 Y=0.37500000 Z=0.37500000
> >>>             MULT= 2          ISPLIT=-2
> >>>         -3: X=0.62500000 Y=0.62500000 Z=0.62500000
> >>> Fe2        NPT=  781  R0=.000050000 RMT=   1.92000   Z:  26.00000
> >>> LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
> >>>                        0.0000000 1.0000000 0.0000000
> >>>                        0.0000000 0.0000000 1.0000000
> >>>     16      NUMBER OF SYMMETRY OPERATIONS
> >>> -1 0 0 0.00000000
> >>>    0-1 0 0.00000000
> >>>    0 0-1 0.00000000
> >>>          1   A   1 so. oper.  type  orig. index
> >>>    1 0 0 0.00000000
> >>>    0 1 0 0.00000000
> >>>    0 0 1 0.00000000
> >>>          2   A  12
> >>>    0-1 0 0.25000000
> >>>    1 0 0 0.00000000
> >>>    0 0-1 0.25000000
> >>>          3   A  15
> >>>    1 0 0 0.75000000
> >>>    0 1 0 0.75000000
> >>>    0 0-1 0.00000000
> >>>          4   A  18
> >>>    0 1 0 0.00000000
> >>> -1 0 0 0.25000000
> >>>    0 0-1 0.25000000
> >>>          5   A  22
> >>> -1 0 0 0.25000000
> >>>    0-1 0 0.25000000
> >>>    0 0 1 0.00000000
> >>>          6   A  33
> >>>    0 1 0 0.75000000
> >>> -1 0 0 0.00000000
> >>>    0 0 1 0.75000000
> >>>          7   A  36
> >>>    0-1 0 0.00000000
> >>>    1 0 0 0.75000000
> >>>    0 0 1 0.75000000
> >>>          8   A  45
> >>>    0-1 0 0.00000000
> >>> -1 0 0 0.00000000
> >>>    0 0-1 0.00000000
> >>>          9   B   3
> >>>    0 1 0 0.00000000
> >>>    1 0 0 0.00000000
> >>>    0 0 1 0.00000000
> >>>         10   B  10
> >>> -1 0 0 0.00000000
> >>>    0 1 0 0.75000000
> >>>    0 0 1 0.75000000
> >>>         11   B  13
> >>>    1 0 0 0.00000000
> >>>    0-1 0 0.25000000
> >>>    0 0-1 0.25000000
> >>>         12   B  14
> >>> -1 0 0 0.25000000
> >>>    0 1 0 0.00000000
> >>>    0 0-1 0.25000000
> >>>         13   B  19
> >>>    0 1 0 0.75000000
> >>>    1 0 0 0.75000000
> >>>    0 0-1 0.00000000
> >>>         14   B  28
> >>>    1 0 0 0.75000000
> >>>    0-1 0 0.00000000
> >>>    0 0 1 0.75000000
> >>>         15   B  32
> >>>    0-1 0 0.25000000
> >>> -1 0 0 0.25000000
> >>>    0 0 1 0.00000000
> >>>         16   B  43
> >>> --------------------Output------------------------------------------------------------------------------
> >>> Fe3O4.outputopup
> >>>
> >>>                                 --------------------------------------------------
> >>>                                    S T R U C T U R A L   I N F O R M A T I O N
> >>>                                 --------------------------------------------------
> >>>
> >>>
> >>>      SUBSTANCE                    = Fe3o4
> >>>       s-o calc. M||  0.00  0.00  1.00
> >>>
> >>>      LATTICE                      = F
> >>>      LATTICE CONSTANTS ARE        =   15.8642570  15.8642570  15.8642570
> >>>      NUMBER OF ATOMS IN UNITCELL  =   3
> >>>      MODE OF CALCULATION IS       = RELA
> >>>      MODUSALL
> >>>      spin-polarized calculation
> >>>      spin-orbit coupling included
> >>>    read inso:
> >>>    theta=  0.000000000000000E+000
> >>>    phi=  0.000000000000000E+000
> >>>    call trans..
> >>>    Transf. matrix:  -1.00000000000000       0.000000000000000E+000
> >>>     0.000000000000000E+000
> >>>    Transf. matrix:  0.000000000000000E+000  -1.00000000000000
> >>>     0.000000000000000E+000
> >>>    Transf. matrix:  0.000000000000000E+000  0.000000000000000E+000
> >>>     -1.00000000000000
> >>>    operation           1
> >>>    det:   1.00000000000000
> >>>    call trans..
> >>>    Transf. matrix:   1.00000000000000       0.000000000000000E+000
> >>>     0.000000000000000E+000
> >>>    Transf. matrix:  0.000000000000000E+000   1.00000000000000
> >>>     0.000000000000000E+000
> >>>    Transf. matrix:  0.000000000000000E+000  0.000000000000000E+000
> >>>      1.00000000000000
> >>>    operation           2
> >>>    det:   1.00000000000000
> >>>    call trans..
> >>>    Transf. matrix:  0.000000000000000E+000   1.00000000000000
> >>>     0.000000000000000E+000
> >>>    Transf. matrix:  -1.00000000000000       0.000000000000000E+000
> >>>     0.000000000000000E+000
> >>>    Transf. matrix:  0.000000000000000E+000  0.000000000000000E+000
> >>>     -1.00000000000000
> >>>    operation           3
> >>>    det:   1.00000000000000
> >>>    call trans..
> >>>    Transf. matrix:   1.00000000000000       0.000000000000000E+000
> >>>     0.000000000000000E+000
> >>>    Transf. matrix:  0.000000000000000E+000   1.00000000000000
> >>>     0.000000000000000E+000
> >>>    Transf. matrix:  0.000000000000000E+000  0.000000000000000E+000
> >>>     -1.00000000000000
> >>>    operation           4
> >>>    det:   1.00000000000000
> >>>    call trans..
> >>>    Transf. matrix:  0.000000000000000E+000  -1.00000000000000
> >>>     0.000000000000000E+000
> >>>    Transf. matrix:   1.00000000000000       0.000000000000000E+000
> >>>     0.000000000000000E+000
> >>>    Transf. matrix:  0.000000000000000E+000  0.000000000000000E+000
> >>>     -1.00000000000000
> >>>    operation           5
> >>>    det:   1.00000000000000
> >>>    call trans..
> >>>    Transf. matrix:  -1.00000000000000       0.000000000000000E+000
> >>>     0.000000000000000E+000
> >>>    Transf. matrix:  0.000000000000000E+000  -1.00000000000000
> >>>     0.000000000000000E+000
> >>>    Transf. matrix:  0.000000000000000E+000  0.000000000000000E+000
> >>>      1.00000000000000
> >>>    operation           6
> >>>    det:   1.00000000000000
> >>>    call trans..
> >>>    Transf. matrix:  0.000000000000000E+000  -1.00000000000000
> >>>     0.000000000000000E+000
> >>>    Transf. matrix:   1.00000000000000       0.000000000000000E+000
> >>>     0.000000000000000E+000
> >>>    Transf. matrix:  0.000000000000000E+000  0.000000000000000E+000
> >>>      1.00000000000000
> >>>    operation           7
> >>>    det:   1.00000000000000
> >>>    call trans..
> >>>    Transf. matrix:  0.000000000000000E+000   1.00000000000000
> >>>     0.000000000000000E+000
> >>>    Transf. matrix:  -1.00000000000000       0.000000000000000E+000
> >>>     0.000000000000000E+000
> >>>    Transf. matrix:  0.000000000000000E+000  0.000000000000000E+000
> >>>      1.00000000000000
> >>>    operation           8
> >>>    det:   1.00000000000000
> >>>    call trans..
> >>>    Transf. matrix:  0.000000000000000E+000  -1.00000000000000
> >>>     0.000000000000000E+000
> >>>    Transf. matrix:  -1.00000000000000       0.000000000000000E+000
> >>>     0.000000000000000E+000
> >>>    Transf. matrix:  0.000000000000000E+000  0.000000000000000E+000
> >>>     -1.00000000000000
> >>>    operation           9
> >>>    det:  -1.00000000000000
> >>>    call trans..
> >>>    Transf. matrix:  0.000000000000000E+000   1.00000000000000
> >>>     0.000000000000000E+000
> >>>    Transf. matrix:   1.00000000000000       0.000000000000000E+000
> >>>     0.000000000000000E+000
> >>>    Transf. matrix:  0.000000000000000E+000  0.000000000000000E+000
> >>>      1.00000000000000
> >>>    operation          10
> >>>    det:  -1.00000000000000
> >>>    call trans..
> >>>    Transf. matrix:  -1.00000000000000       0.000000000000000E+000
> >>>     0.000000000000000E+000
> >>>    Transf. matrix:  0.000000000000000E+000   1.00000000000000
> >>>     0.000000000000000E+000
> >>>    Transf. matrix:  0.000000000000000E+000  0.000000000000000E+000
> >>>      1.00000000000000
> >>>    operation          11
> >>>    det:  -1.00000000000000
> >>>    call trans..
> >>>    Transf. matrix:   1.00000000000000       0.000000000000000E+000
> >>>     0.000000000000000E+000
> >>>    Transf. matrix:  0.000000000000000E+000  -1.00000000000000
> >>>     0.000000000000000E+000
> >>>    Transf. matrix:  0.000000000000000E+000  0.000000000000000E+000
> >>>     -1.00000000000000
> >>>    operation          12
> >>>    det:  -1.00000000000000
> >>>    call trans..
> >>>    Transf. matrix:  -1.00000000000000       0.000000000000000E+000
> >>>     0.000000000000000E+000
> >>>    Transf. matrix:  0.000000000000000E+000   1.00000000000000
> >>>     0.000000000000000E+000
> >>>    Transf. matrix:  0.000000000000000E+000  0.000000000000000E+000
> >>>     -1.00000000000000
> >>>    operation          13
> >>>    det:  -1.00000000000000
> >>>    call trans..
> >>>    Transf. matrix:  0.000000000000000E+000   1.00000000000000
> >>>     0.000000000000000E+000
> >>>    Transf. matrix:   1.00000000000000       0.000000000000000E+000
> >>>     0.000000000000000E+000
> >>>    Transf. matrix:  0.000000000000000E+000  0.000000000000000E+000
> >>>     -1.00000000000000
> >>>    operation          14
> >>>    det:  -1.00000000000000
> >>>    call trans..
> >>>    Transf. matrix:   1.00000000000000       0.000000000000000E+000
> >>>     0.000000000000000E+000
> >>>    Transf. matrix:  0.000000000000000E+000  -1.00000000000000
> >>>     0.000000000000000E+000
> >>>    Transf. matrix:  0.000000000000000E+000  0.000000000000000E+000
> >>>      1.00000000000000
> >>>    operation          15
> >>>    det:  -1.00000000000000
> >>>    call trans..
> >>>    Transf. matrix:  0.000000000000000E+000  -1.00000000000000
> >>>     0.000000000000000E+000
> >>>    Transf. matrix:  -1.00000000000000       0.000000000000000E+000
> >>>     0.000000000000000E+000
> >>>    Transf. matrix:  0.000000000000000E+000  0.000000000000000E+000
> >>>      1.00000000000000
> >>>    operation          16
> >>>    det:  -1.00000000000000
> >>> ----------------------------error
> >>> files---------------------------------------------
> >>> upoptic.error
> >>> Error in OPTIC
> >>> _______________________________________________
> >>> Wien mailing list
> >>> Wien at zeus.theochem.tuwien.ac.at
> >>> http://zeus.theochem.tuwien.ac.at/mailman/listinfo/wien
> >>> SEARCH the MAILING-LIST at:  http://www.mail-archive.com/wien@zeus.theochem.tuwien.ac.at/index.html
> >>>
> >>
> >> --
> >> --------------------------------------------------------------------------
> >> Peter BLAHA, Inst.f. Materials Chemistry, TU Vienna, A-1060 Vienna
> >> Phone: +43-1-58801-165300             FAX: +43-1-58801-165982
> >> Email: blaha at theochem.tuwien.ac.at    WIEN2k: http://www.wien2k.at
> >> WWW:
> >> http://www.imc.tuwien.ac.at/tc_blaha-------------------------------------------------------------------------
> >>
> >> _______________________________________________
> >> Wien mailing list
> >> Wien at zeus.theochem.tuwien.ac.at
> >> http://zeus.theochem.tuwien.ac.at/mailman/listinfo/wien
> >> SEARCH the MAILING-LIST at:  http://www.mail-archive.com/wien@zeus.theochem.tuwien.ac.at/index.html
> > _______________________________________________
> > Wien mailing list
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> > SEARCH the MAILING-LIST at:  http://www.mail-archive.com/wien@zeus.theochem.tuwien.ac.at/index.html
> >
>
> --
>
>                                        P.Blaha
> --------------------------------------------------------------------------
> Peter BLAHA, Inst.f. Materials Chemistry, TU Vienna, A-1060 Vienna
> Phone: +43-1-58801-165300             FAX: +43-1-58801-165982
> Email: blaha at theochem.tuwien.ac.at    WIEN2k: http://www.wien2k.at
> WWW:   http://www.imc.tuwien.ac.at/TC_Blaha
> --------------------------------------------------------------------------
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