[Wien] Irrep output file

Peter Blaha pblaha at theochem.tuwien.ac.at
Mon Jun 29 07:28:43 CEST 2020


Hi

Yes of course.  RLOs are not supported in auxiliary programs.

This is a typical example of "not providing enough information" for an 
efficient help.

On 6/29/20 1:09 AM, Md. Fhokrul Islam wrote:
> Hi Prof. Blaha,
> 
> I think the problem is probably with RLO orbitals. If I initialize 
> spin-orbit without RLO then I get correct irrep. It works for both 
> Wien2k_18.2 and 19.2.
> 
> 
> Thanks,
> Fhokrul
> 
> 
> 
> 
> 
> 
> ------------------------------------------------------------------------
> *From:* Wien <wien-bounces at zeus.theochem.tuwien.ac.at> on behalf of 
> Peter Blaha <pblaha at theochem.tuwien.ac.at>
> *Sent:* Monday, June 22, 2020 8:44 AM
> *To:* wien at zeus.theochem.tuwien.ac.at <wien at zeus.theochem.tuwien.ac.at>
> *Subject:* Re: [Wien] Irrep output file
> I don't know where the problem is.
> 
> I used your struct file, initialized and did a non-scf
> 
> x lapw0
> x lapw1 -band
> x lapwso
> x irrep -so
> 
> There are no problems in outputirso. All irreps could be found, but
> please note, this is NOT scf !
> 
> knum =  1    kname= Z
> k = 0.000000 0.000000 0.500000
> 
>          The point group is Ci
> ....
> bnd ndg  eigval     E           I
>     1  2 -4.585464 2.00+0.00i  2.00+0.00i =G2+ + G2+
>     3  2 -4.585396 2.00-0.00i -2.00+0.00i =G2- + G2-
>     5  2 -4.585388 2.00+0.00i  2.00+0.00i =G2+ + G2+
>     7  2 -4.585374 2.00-0.00i -2.00-0.00i =G2- + G2-
>     9  2 -4.585243 2.00-0.00i -2.00+0.00i =G2- + G2-
> 
>    97  2 -4.173640 2.00-0.00i  2.00-0.00i =G2+ + G2+
>    99  2 -4.173630 2.00+0.00i -2.00+0.00i =G2- + G2-
> 101  2 -4.173574 2.00-0.00i -2.00+0.00i =G2- + G2-
> 103  2 -4.173567 2.00-0.00i  2.00-0.00i =G2+ + G2+
> 105  2 -4.173461 2.00-0.00i  2.00-0.00i =G2+ + G2+
> 107  2 -4.173453 2.00-0.00i -2.00+0.00i =G2- + G2-
> 109  2 -4.172885 2.00+0.00i  2.00-0.00i =G2+ + G2+
> 111  2 -4.172854 2.00-0.00i -2.00-0.00i =G2- + G2-
> 113  2 -4.172846 2.00+0.00i  2.00+0.00i =G2+ + G2+
> 115  2 -4.172820 2.00-0.00i -2.00+0.00i =G2- + G2-
> 117  2 -4.172695 2.00-0.00i -2.00+0.00i =G2- + G2-
> 119  2 -4.172669 2.00+0.00i  2.00+0.00i =G2+ + G2+
> 121  2 -2.391230 2.00-0.00i  2.00-0.00i =G2+ + G2+
> 123  2 -2.391209 2.00-0.00i -2.00+0.00i =G2- + G2-
> 125  2 -2.390878 2.00-0.00i  2.00-0.00i =G2+ + G2+
> 127  2 -2.390873 2.00+0.00i -2.00-0.00i =G2- + G2-
> 
> 
> Maybe update to the most recent WIEN2k version.
> 
> Am 20.06.2020 um 21:37 schrieb Md. Fhokrul Islam:
>> Dear users,
>> 
>> I am trying to extract irreducible representation of eigenvalues. I have 
>> obtained the case.outputirso and case.irrepso files. But I am not sure 
>> if I understood these files correctly. The Ci point group has two 
>> irreducible representations as listed in the file but many of the 
>> eigenstates are labelled by "??". Am I doing anything wrong? The bands 
>> 105 -108 are four-fold degenerate with irrep of the double group G2+, 
>> G2+,G2-,G2-, respectively, right? Also, can anyone please clarify what 
>> are the complex numbers under operators E and I?
>> 
>> 
>> Case. outputirso:
>> 
>>         The point group is Ci
>>         2 symmetry operations in  2 classes
>>         Table  6   on page  32 in Koster  et al [7]
>>         Table 11.4 on page 138 in Altmann et al [8]
>> 
>>                             E     I
>>         G1+   A1g    1     1
>>         G1-    A1u    1    -1
>>         --------------------
>>         G2+  A1/2g  1     1
>>         G2-   A1/2u  1    -1
>> 
>> 
>> class, symmetry ops, exp(-i*k*taui)
>>     E    2             (+1.00 0.00i)
>>      I    1             (+1.00 0.00i)
>> 
>> bnd ndg  eigval     E                   I
>>    1  2 -4.675588 1.99+0.00i -1.99-0.00i  ??
>>    3  2 -4.675572 1.99-0.00i   1.99-0.00i  ??
>>    5  2 -4.674606 1.98-0.00i  -1.98+0.00i ??
>> ...
>> ...
>>   97  4 -4.261267 3.97+0.00i -0.00-0.00i  ??
>> 101  4 -4.261167 3.99-0.00i  0.01+0.00i  ??
>> 105  4 -4.260795 4.00-0.00i  0.00+0.00i =G2+ + G2+ + G2- + G2-
>> 109  4 -4.259344 3.99-0.00i  0.00+0.00i ??
>> 113  4 -4.258747 4.00+0.00i  0.00-0.00i =G2+ + G2+ + G2- + G2-
>> 117  4 -4.258715 4.00-0.00i  0.00+0.00i =G2+ + G2+ + G2- + G2-
>> 121  4 -2.333313 3.90-0.00i -0.01-0.00i ??
>> 125  4 -2.333098 4.00+0.00i -0.00-0.00i =G2+ + G2+ + G2- + G2-
>> 129  4 -2.332321 3.93+0.00i -0.02+0.00i ??
>> 
>> The corresponding bands in the case.irrepso file:
>> ....
>>         104         4  -4.261165    0  0    0  0    0  0    0  0
>>         105         4  -4.260795    2  1    2  1   -2  1   -2  1
>>         106         4  -4.260795    2  1    2  1   -2  1   -2  1
>>         107         4  -4.260791    2  1    2  1   -2  1   -2  1
>>         108         4  -4.260791    2  1    2  1   -2  1   -2  1
>>         109         4  -4.259344    0  0    0  0    0  0    0  0
>>         110         4  -4.259344    0  0    0  0    0  0    0  0
>> ....
>> 
>> What are the numbers in column 4-7?
>> 
>> Thanks,
>> Fhokrul
>> 
>> 
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> 
> -- 
> Peter Blaha
> Inst.Materials Chemistry
> TU Vienna
> Getreidemarkt 9
> A-1060 Vienna
> Austria
> +43-1-5880115671
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-- 

                                       P.Blaha
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Peter BLAHA, Inst.f. Materials Chemistry, TU Vienna, A-1060 Vienna
Phone: +43-1-58801-165300             FAX: +43-1-58801-165982
Email: blaha at theochem.tuwien.ac.at    WIEN2k: http://www.wien2k.at
WWW:   http://www.imc.tuwien.ac.at/TC_Blaha
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