[Wien] Error in MoS2 doped with Ti

Gavin Abo gabo13279 at gmail.com
Tue Jul 5 01:33:26 CEST 2022


You might try the attached MoS2-Ti.struct which was generated by 
sgroup.  Though, you will probably want to double-check it for example 
in XCrySDen or VESTA to ensure that it still looks right.


The previous MoS2-Ti.struct that you sent stops with an error "STOP 2 
missing" in "x symmetry" for me. However, if I take struct file that was 
produced by sgroup, the initialization seems to finish fine.  The exact 
commands and output in a bash terminal are below (note: some of the 
output that didn't seem relevant I cut out so that it could be posted 
the mailing list):


username at computername:~/wiendata/MoS2-Ti$ ls -l
total 12
-rw-r--r-- 1 username username 8825 Jul  4 11:14 MoS2-Ti.struct
username at computername:~/wiendata/MoS2-Ti$ x nn
  specify nn-bondlength factor: (usually=2) [and optionally dlimit, 
dstmax (about 1.d-5, 20)]
2
...
     ATOM 22  Ti1        ATOM  9  S 2
  RMT( 22)=2.07000 AND RMT(  9)=1.78000
  SUMS TO 3.85000  LT.  NN-DIST= 3.87254
STOP NN ENDS
0.288u 0.016s 0:01.48 19.5%    0+0k 0+720io 0pf+0w
username at computername:~/wiendata/MoS2-Ti$ x sgroup
0.005u 0.000s 0:00.00 0.0%    0+0k 0+24io 0pf+0w
username at computername:~/wiendata/MoS2-Ti$ x symmetry
  SPACE GROUP DOES NOT CONTAIN INVERSION
STOP 2 missing
0.021u 0.010s 0:00.03 100.0%    0+0k 0+104io 0pf+0w'
username at computername:~/wiendata/MoS2-Ti$ cp MoS2-Ti.struct_sgroup 
MoS2-Ti.struct
username at computername:~/wiendata/MoS2-Ti$ x symmetry
  SPACE GROUP DOES NOT CONTAIN INVERSION
0.042u 0.007s 0:00.05 80.0%    0+0k 0+128io 0pf+0w
username at computername:~/wiendata/MoS2-Ti$ init_lapw -b
...
   init_lapw finished ok


Kind Regards,

Gavin

WIEN2k user


On 7/4/2022 4:41 PM, delamora wrote:
> Dear Gavin,
> Thank you for your reply, but I still get the same problem;
> In the last struct file I did the supercell and added the Ti atom, but 
> afterwards I did not calculated the Rmt.
> Now in this struct I that I include here I did it and I get
> Rmt Mo; 2.41, S; 1.78, Ti; 2.07
>
> Then with "init" I get this message
> --------------------
> next is kgen
> >   kgen (17:33:38) forrtl: severe (24): end-of-file during read, unit 
> 20, file /home/pablo/WIEN2k/MoS2-Ti/MoS2-Ti.struct
> Image              PC                Routine  Line        Source
> kgen               000000000045C74B  Unknown Unknown  Unknown
> kgen               0000000000425E78  Unknown Unknown  Unknown
> kgen               00000000004047B5  MAIN__    195  main.f
> kgen               00000000004041B2  Unknown Unknown  Unknown
> libc-2.24.so       00001500989F3431  __libc_start_main Unknown  Unknown
> kgen               00000000004040AA  Unknown Unknown  Unknown
> 0.001u 0.000s 0:00.00 0.0% 0+0k 0+0io 0pf+0w
> error: command   /home/Programas/WIEN2k-19.1/kgen kgen.def   failed
>  \n stop error \n
> --------------------
> or with the WIEN2k interface I still get a problem;
> --------------------
> >   inputfiles for lapw1c/2c prepared, no inversion present	(17:35:21)  
>   next is kgen
> forrtl: severe (24): end-of-file during read, unit 20, file /home/pablo/WIEN2k/MoS2-Ti/MoS2-Ti.struct
> Image              PC                Routine            Line        Source
> kgen               000000000045C74B  Unknown               Unknown  Unknown
> kgen               0000000000425E78  Unknown               Unknown  Unknown
> kgen               00000000004047B5  MAIN__                    195  main.f
> kgen               00000000004041B2  Unknown               Unknown  Unknown
> libc-2.24.so       000014A887F27431  __libc_start_main     Unknown  Unknown
> kgen               00000000004040AA  Unknown               Unknown  Unknown
>   \n stop error \n
> ----------------------------------
>
> I am using versions 19.1 and 21.1 with fedora
>
> Cheers
>
> Pablo
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Title                                                                          
H   LATTICE,NONEQUIV.ATOMS: 22 156 P3m1                                        
MODE OF CALC=RELA unit=ang                                                     
 17.959965 17.959965 23.285215 90.000000 90.000000120.000000                   
ATOM  -1: X=0.55555555 Y=0.77777778 Z=0.50000000
          MULT= 3          ISPLIT= 8
      -1: X=0.22222222 Y=0.77777777 Z=0.50000000
      -1: X=0.22222223 Y=0.44444445 Z=0.50000000
Mo1        NPT=  781  R0=0.00001000 RMT= 2.31        Z: 42.0                   
LOCAL ROT MATRIX:    0.0000000 1.0000000 0.0000000
                     0.0000000 0.0000000 1.0000000
                     1.0000000 0.0000000 0.0000000
ATOM  -2: X=0.00000000 Y=0.66666667 Z=0.00000000
          MULT= 6          ISPLIT= 8
      -2: X=0.33333333 Y=0.33333333 Z=0.00000000
      -2: X=0.66666667 Y=0.00000000 Z=0.00000000
      -2: X=0.33333333 Y=0.00000000 Z=0.00000000
      -2: X=0.66666667 Y=0.66666667 Z=0.00000000
      -2: X=0.00000000 Y=0.33333333 Z=0.00000000
Mo2        NPT=  781  R0=0.00001000 RMT= 2.31        Z: 42.0                   
LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                     0.0000000 1.0000000 0.0000000
                     0.0000000 0.0000000 1.0000000
ATOM  -3: X=0.00000000 Y=0.00000000 Z=0.00000000
          MULT= 1          ISPLIT= 4
Mo3        NPT=  781  R0=0.00001000 RMT= 2.31        Z: 42.0                   
LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                     0.0000000 1.0000000 0.0000000
                     0.0000000 0.0000000 1.0000000
ATOM  -4: X=0.22222222 Y=0.11111112 Z=0.50000000
          MULT= 3          ISPLIT= 8
      -4: X=0.88888888 Y=0.11111110 Z=0.50000000
      -4: X=0.88888890 Y=0.77777778 Z=0.50000000
Mo4        NPT=  781  R0=0.00001000 RMT= 2.31        Z: 42.0                   
LOCAL ROT MATRIX:    0.0000000 1.0000000 0.0000000
                     0.0000000 0.0000000 1.0000000
                     1.0000000 0.0000000 0.0000000
ATOM  -5: X=0.66666666 Y=0.33333334 Z=0.00000000
          MULT= 1          ISPLIT= 4
Mo5        NPT=  781  R0=0.00001000 RMT= 2.31        Z: 42.0                   
LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                     0.0000000 1.0000000 0.0000000
                     0.0000000 0.0000000 1.0000000
ATOM  -6: X=0.88888888 Y=0.44444445 Z=0.50000000
          MULT= 3          ISPLIT= 8
      -6: X=0.55555555 Y=0.44444443 Z=0.50000000
      -6: X=0.55555557 Y=0.11111112 Z=0.50000000
Mo6        NPT=  781  R0=0.00001000 RMT= 2.31        Z: 42.0                   
LOCAL ROT MATRIX:    0.0000000 1.0000000 0.0000000
                     0.0000000 0.0000000 1.0000000
                     1.0000000 0.0000000 0.0000000
ATOM  -7: X=0.33333333 Y=0.66666667 Z=0.00000000
          MULT= 1          ISPLIT= 4
Mo7        NPT=  781  R0=0.00001000 RMT= 2.31        Z: 42.0                   
LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                     0.0000000 1.0000000 0.0000000
                     0.0000000 0.0000000 1.0000000
ATOM  -8: X=0.55555555 Y=0.77777778 Z=0.87500000
          MULT= 3          ISPLIT= 8
      -8: X=0.22222222 Y=0.77777777 Z=0.87500000
      -8: X=0.22222223 Y=0.44444445 Z=0.87500000
S 1        NPT=  781  R0=0.00010000 RMT= 1.78        Z: 16.0                   
LOCAL ROT MATRIX:    0.0000000 1.0000000 0.0000000
                     0.0000000 0.0000000 1.0000000
                     1.0000000 0.0000000 0.0000000
ATOM  -9: X=0.55555555 Y=0.77777778 Z=0.12500000
          MULT= 3          ISPLIT= 8
      -9: X=0.22222222 Y=0.77777777 Z=0.12500000
      -9: X=0.22222223 Y=0.44444445 Z=0.12500000
S 2        NPT=  781  R0=0.00010000 RMT= 1.78        Z: 16.0                   
LOCAL ROT MATRIX:    0.0000000 1.0000000 0.0000000
                     0.0000000 0.0000000 1.0000000
                     1.0000000 0.0000000 0.0000000
ATOM -10: X=0.00000000 Y=0.66666667 Z=0.37500000
          MULT= 6          ISPLIT= 8
     -10: X=0.33333333 Y=0.33333333 Z=0.37500000
     -10: X=0.66666667 Y=0.00000000 Z=0.37500000
     -10: X=0.33333333 Y=0.00000000 Z=0.37500000
     -10: X=0.66666667 Y=0.66666667 Z=0.37500000
     -10: X=0.00000000 Y=0.33333333 Z=0.37500000
S 3        NPT=  781  R0=0.00010000 RMT= 1.78        Z: 16.0                   
LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                     0.0000000 1.0000000 0.0000000
                     0.0000000 0.0000000 1.0000000
ATOM -11: X=0.55555555 Y=0.11111112 Z=0.87500000
          MULT= 3          ISPLIT= 8
     -11: X=0.88888888 Y=0.44444443 Z=0.87500000
     -11: X=0.55555557 Y=0.44444445 Z=0.87500000
S 4        NPT=  781  R0=0.00010000 RMT= 1.78        Z: 16.0                   
LOCAL ROT MATRIX:   -0.0000000-0.5000000 0.8660254
                     0.0000000-0.8660254-0.5000000
                     1.0000000 0.0000000 0.0000000
ATOM -12: X=0.55555555 Y=0.11111112 Z=0.12500000
          MULT= 3          ISPLIT= 8
     -12: X=0.88888888 Y=0.44444443 Z=0.12500000
     -12: X=0.55555557 Y=0.44444445 Z=0.12500000
S 5        NPT=  781  R0=0.00010000 RMT= 1.78        Z: 16.0                   
LOCAL ROT MATRIX:   -0.0000000-0.5000000 0.8660254
                     0.0000000-0.8660254-0.5000000
                     1.0000000 0.0000000 0.0000000
ATOM -13: X=0.00000000 Y=0.00000000 Z=0.37500000
          MULT= 1          ISPLIT= 4
S 6        NPT=  781  R0=0.00010000 RMT= 1.78        Z: 16.0                   
LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                     0.0000000 1.0000000 0.0000000
                     0.0000000 0.0000000 1.0000000
ATOM -14: X=0.88888889 Y=0.11111112 Z=0.12500000
          MULT= 3          ISPLIT= 8
     -14: X=0.88888888 Y=0.77777777 Z=0.12500000
     -14: X=0.22222223 Y=0.11111111 Z=0.12500000
S 7        NPT=  781  R0=0.00010000 RMT= 1.78        Z: 16.0                   
LOCAL ROT MATRIX:   -0.0000000 0.5000000 0.8660254
                     0.0000000-0.8660254 0.5000000
                     1.0000000 0.0000000 0.0000000
ATOM -15: X=0.33333333 Y=0.66666667 Z=0.62500000
          MULT= 1          ISPLIT= 4
S 8        NPT=  781  R0=0.00010000 RMT= 1.78        Z: 16.0                   
LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                     0.0000000 1.0000000 0.0000000
                     0.0000000 0.0000000 1.0000000
ATOM -16: X=0.33333333 Y=0.00000000 Z=0.62500000
          MULT= 6          ISPLIT= 8
     -16: X=0.00000000 Y=0.33333333 Z=0.62500000
     -16: X=0.66666667 Y=0.66666667 Z=0.62500000
     -16: X=0.00000000 Y=0.66666667 Z=0.62500000
     -16: X=0.66666667 Y=0.00000000 Z=0.62500000
     -16: X=0.33333333 Y=0.33333333 Z=0.62500000
S 9        NPT=  781  R0=0.00010000 RMT= 1.78        Z: 16.0                   
LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                     0.0000000 1.0000000 0.0000000
                     0.0000000 0.0000000 1.0000000
ATOM -17: X=0.66666666 Y=0.33333334 Z=0.62500000
          MULT= 1          ISPLIT= 4
S 10       NPT=  781  R0=0.00010000 RMT= 1.78        Z: 16.0                   
LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                     0.0000000 1.0000000 0.0000000
                     0.0000000 0.0000000 1.0000000
ATOM -18: X=0.88888888 Y=0.77777778 Z=0.87500000
          MULT= 3          ISPLIT= 8
     -18: X=0.22222222 Y=0.11111110 Z=0.87500000
     -18: X=0.88888890 Y=0.11111112 Z=0.87500000
S 11       NPT=  781  R0=0.00010000 RMT= 1.78        Z: 16.0                   
LOCAL ROT MATRIX:   -0.0000000-0.5000000 0.8660254
                     0.0000000-0.8660254-0.5000000
                     1.0000000 0.0000000 0.0000000
ATOM -19: X=0.00000000 Y=0.00000000 Z=0.62500000
          MULT= 1          ISPLIT= 4
S 12       NPT=  781  R0=0.00010000 RMT= 1.78        Z: 16.0                   
LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                     0.0000000 1.0000000 0.0000000
                     0.0000000 0.0000000 1.0000000
ATOM -20: X=0.33333333 Y=0.66666667 Z=0.37500000
          MULT= 1          ISPLIT= 4
S 13       NPT=  781  R0=0.00010000 RMT= 1.78        Z: 16.0                   
LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                     0.0000000 1.0000000 0.0000000
                     0.0000000 0.0000000 1.0000000
ATOM -21: X=0.66666666 Y=0.33333334 Z=0.37500000
          MULT= 1          ISPLIT= 4
S 14       NPT=  781  R0=0.00010000 RMT= 1.78        Z: 16.0                   
LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                     0.0000000 1.0000000 0.0000000
                     0.0000000 0.0000000 1.0000000
ATOM -22: X=0.33333333 Y=0.66666667 Z=0.20000000
          MULT= 1          ISPLIT= 4
Ti1        NPT=  781  R0=0.00005000 RMT= 2.07        Z: 22.0                   
LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                     0.0000000 1.0000000 0.0000000
                     0.0000000 0.0000000 1.0000000
   6      NUMBER OF SYMMETRY OPERATIONS
 1 0 0 0.00000000
 0 1 0 0.00000000
 0 0 1 0.00000000
       1
 0-1 0 0.00000000
 1-1 0 0.00000000
 0 0 1 0.00000000
       2
-1 1 0 0.00000000
-1 0 0 0.00000000
 0 0 1 0.00000000
       3
 0-1 0 0.00000000
-1 0 0 0.00000000
 0 0 1 0.00000000
       4
-1 1 0 0.00000000
 0 1 0 0.00000000
 0 0 1 0.00000000
       5
 1 0 0 0.00000000
 1-1 0 0.00000000
 0 0 1 0.00000000
       6


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