[Wien] CuO crash

Peter Blaha peter.blaha at tuwien.ac.at
Fri Nov 10 12:05:45 CET 2023


i) You need to send small emails (below 40k). Remove old replies from 
your mail.

ii) CuO is an antiferromagnet. Did you set case.inst properly (eg. by 
instgen -ask) ? You have to know which Cu atom has spin-up and which one 
spin-dn.
Did you do a proper AFM calculation of CuO first and compared to 
literature, so that you know you are doing all-right ?

iii) You made a typo for the U value of Mn (   0.0.45569 0.00)

iv) For the error: Check the *.error files and also case.dayfile, 
case.output1up*

Regards
Peter Blaha

----------------------------------------------

Betreff: Re: Wien Digest, Vol 214, Issue 1
Von: Murat Aycibin <aycibin at gmail.com>
Datum: 10.11.2023, 09:36

Thanks for Repliying
I have followed process like below
I constructed struct file f for 2*2*1 super cell of CuO. after that i 
changed one of Cu with Mn firstly. and then i performed initial 
calculation including spin polarization option. The struct file ( after 
Mn doped) is
CS 

P   LATTICE,NONEQUIV.ATOMS: 18 2 P-1 

MODE OF CALC=RELA unit=ang 

   6.413355 17.631152 19.490644 99.540000 90.000000 90.000000
ATOM  -1: X=0.00000000 Y=0.75000000 Z=0.75000000
           MULT= 2          ISPLIT= 8
       -1: X=0.00000000 Y=0.25000000 Z=0.25000000
Cu1        NPT=  781  R0=0.00005000 RMT=    1.8700   Z: 29.0 

LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                      0.0000000 1.0000000 0.0000000
                      0.0000000 0.0000000 1.0000000
ATOM  -2: X=0.00000000 Y=0.50000000 Z=0.00000000
           MULT= 1          ISPLIT= 8
Cu2        NPT=  781  R0=0.00005000 RMT=    1.8700   Z: 29.0 

LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                      0.0000000 1.0000000 0.0000000
                      0.0000000 0.0000000 1.0000000
ATOM  -3: X=0.00000000 Y=0.75000000 Z=0.25000000
           MULT= 2          ISPLIT= 8
       -3: X=0.00000000 Y=0.25000000 Z=0.75000000
Cu3        NPT=  781  R0=0.00005000 RMT=    1.8700   Z: 29.0 

LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                      0.0000000 1.0000000 0.0000000
                      0.0000000 0.0000000 1.0000000
ATOM  -4: X=0.00000000 Y=0.00000000 Z=0.50000000
           MULT= 1          ISPLIT= 8
Cu4        NPT=  781  R0=0.00005000 RMT=    1.8700   Z: 29.0 

LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                      0.0000000 1.0000000 0.0000000
                      0.0000000 0.0000000 1.0000000
ATOM  -5: X=0.00000000 Y=0.50000000 Z=0.50000000
           MULT= 1          ISPLIT= 8
Cu5        NPT=  781  R0=0.00005000 RMT=    1.8700   Z: 29.0 

LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                      0.0000000 1.0000000 0.0000000
                      0.0000000 0.0000000 1.0000000
ATOM  -6: X=0.50000000 Y=0.00000000 Z=0.75000000
           MULT= 2          ISPLIT= 8
       -6: X=0.50000000 Y=0.00000000 Z=0.25000000
Cu6        NPT=  781  R0=0.00005000 RMT=    1.8700   Z: 29.0 

LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                      0.0000000 1.0000000 0.0000000
                      0.0000000 0.0000000 1.0000000
ATOM  -7: X=0.50000000 Y=0.50000000 Z=0.75000000
           MULT= 2          ISPLIT= 8
       -7: X=0.50000000 Y=0.50000000 Z=0.25000000
Cu7        NPT=  781  R0=0.00005000 RMT=    1.8700   Z: 29.0 

LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                      0.0000000 1.0000000 0.0000000
                      0.0000000 0.0000000 1.0000000
ATOM  -8: X=0.50000000 Y=0.75000000 Z=0.00000000
           MULT= 2          ISPLIT= 8
       -8: X=0.50000000 Y=0.25000000 Z=0.00000000
Cu8        NPT=  781  R0=0.00005000 RMT=    1.8700   Z: 29.0 

LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                      0.0000000 1.0000000 0.0000000
                      0.0000000 0.0000000 1.0000000
ATOM  -9: X=0.50000000 Y=0.75000000 Z=0.50000000
           MULT= 2          ISPLIT= 8
       -9: X=0.50000000 Y=0.25000000 Z=0.50000000
Cu9        NPT=  781  R0=0.00005000 RMT=    1.8700   Z: 29.0 

LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                      0.0000000 1.0000000 0.0000000
                      0.0000000 0.0000000 1.0000000
ATOM -10: X=0.16700000 Y=0.62500000 Z=0.87500000
           MULT= 2          ISPLIT= 8
      -10: X=0.83300000 Y=0.37500000 Z=0.12500000
O 1        NPT=  781  R0=0.00010000 RMT=    1.6100   Z:  8.0 

LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                      0.0000000 1.0000000 0.0000000
                      0.0000000 0.0000000 1.0000000
ATOM -11: X=0.16700000 Y=0.12500000 Z=0.87500000
           MULT= 2          ISPLIT= 8
      -11: X=0.83300000 Y=0.87500000 Z=0.12500000
O 2        NPT=  781  R0=0.00010000 RMT=    1.6100   Z:  8.0 

LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                      0.0000000 1.0000000 0.0000000
                      0.0000000 0.0000000 1.0000000
ATOM -12: X=0.16700000 Y=0.62500000 Z=0.37500000
           MULT= 2          ISPLIT= 8
      -12: X=0.83300000 Y=0.37500000 Z=0.62500000
O 3        NPT=  781  R0=0.00010000 RMT=    1.6100   Z:  8.0 

LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                      0.0000000 1.0000000 0.0000000
                      0.0000000 0.0000000 1.0000000
ATOM -13: X=0.16700000 Y=0.12500000 Z=0.37500000
           MULT= 2          ISPLIT= 8
      -13: X=0.83300000 Y=0.87500000 Z=0.62500000
O 4        NPT=  781  R0=0.00010000 RMT=    1.6100   Z:  8.0 

LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                      0.0000000 1.0000000 0.0000000
                      0.0000000 0.0000000 1.0000000
ATOM -14: X=0.66700000 Y=0.87500000 Z=0.87500000
           MULT= 2          ISPLIT= 8
      -14: X=0.33300000 Y=0.12500000 Z=0.12500000
O 5        NPT=  781  R0=0.00010000 RMT=    1.6100   Z:  8.0 

LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                      0.0000000 1.0000000 0.0000000
                      0.0000000 0.0000000 1.0000000
ATOM -15: X=0.66700000 Y=0.37500000 Z=0.87500000
           MULT= 2          ISPLIT= 8
      -15: X=0.33300000 Y=0.62500000 Z=0.12500000
O 6        NPT=  781  R0=0.00010000 RMT=    1.6100   Z:  8.0 

LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                      0.0000000 1.0000000 0.0000000
                      0.0000000 0.0000000 1.0000000
ATOM -16: X=0.66700000 Y=0.87500000 Z=0.37500000
           MULT= 2          ISPLIT= 8
      -16: X=0.33300000 Y=0.12500000 Z=0.62500000
O 7        NPT=  781  R0=0.00010000 RMT=    1.6100   Z:  8.0 

LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                      0.0000000 1.0000000 0.0000000
                      0.0000000 0.0000000 1.0000000
ATOM -17: X=0.66700000 Y=0.37500000 Z=0.37500000
           MULT= 2          ISPLIT= 8
      -17: X=0.33300000 Y=0.62500000 Z=0.62500000
O 8        NPT=  781  R0=0.00010000 RMT=    1.6100   Z:  8.0 

LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                      0.0000000 1.0000000 0.0000000
                      0.0000000 0.0000000 1.0000000
ATOM -18: X=0.00000000 Y=0.00000000 Z=0.00000000
           MULT= 1          ISPLIT= 8
Mn1        NPT=  781  R0=0.00005000 RMT=    1.8700   Z: 25.0 

LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                      0.0000000 1.0000000 0.0000000
                      0.0000000 0.0000000 1.0000000
    2      NUMBER OF SYMMETRY OPERATIONS
  1 0 0 0.00000000
  0 1 0 0.00000000
  0 0 1 0.00000000
        1
-1 0 0 0.00000000
  0-1 0 0.00000000
  0 0-1 0.00000000
        2

Then The ı prepared
-12.                      Emin cutoff energy
  10                       number of atoms for which density matrix is 
calculated
  1  1  2      index of 1st atom, number of L's, L1
  2  1  2      ditto for 2nd atom, repeat NATOM times
  3  1  2
  4  1  2
  5  1  2
  6  1  2
  7  1  2
  8  1  2
  9  1  2
  18  1  2
  0 0           r-index, (l,s)index
and *.inorb file
   1  10  0                     nmod, natorb, ipr
PRATT  1.0                    BROYD/PRATT, mixing
   1 1 2                          iatom nlorb, lorb
   2 1 2                          iatom nlorb, lorb
   3 1 2
   4 1 2
   5 1 2
   6 1 2
   7 1 2
   8 1 2
   9 1 2
   18 1 2
   1                              nsic 0..AMF, 1..SIC, 2..HFM
    0.36749 0.00        U J (Ry)   Note: you can also use U_eff = U-J 
and J=0
    0.36749 0.00        U J
    0.36749 0.00
    0.36749 0.00
    0.36749 0.00
    0.36749 0.00
    0.36749 0.00
    0.36749 0.00
    0.36749 0.00
    0.0.45569 0.00
After that i perforned spin polarize scf then i get

  LAPW0 END
LAPW1 - Error
[1]  + Done                          ( cd $PWD; $t $exe 
${def}_$loop.def; rm -f .lock_$lockfile[$p] ) >> .time1_$loop
LAPW1 - Error
[1]  + Done                          ( cd $PWD; $t $exe 
${def}_$loop.def; rm -f .lock_$lockfile[$p] ) >> .time1_$loop
LAPW1 - Error
[1]  + Done                          ( cd $PWD; $t $exe 
${def}_$loop.def; rm -f .lock_$lockfile[$p] ) >> .time1_$loop
LAPW1 - Error
[1]  + Done                          ( cd $PWD; $t $exe 
${def}_$loop.def; rm -f .lock_$lockfile[$p] ) >> .time1_$loop
CM.scf1up_1: No such file or directory.
grep: No match.
grep: No match.
grep: No match.
grep: No match.
grep: No match.
grep: No match.
grep: No match.
grep: No match.
grep: No match.

 >   stop error

What should ı do



-- 
--------------------------------------------------------------------------
Peter BLAHA, Inst.f. Materials Chemistry, TU Vienna, A-1060 Vienna
Phone: +43-1-58801-165300
Email: peter.blaha at tuwien.ac.at    WIEN2k: http://www.wien2k.at
WWW:   http://www.imc.tuwien.ac.at
-------------------------------------------------------------------------


More information about the Wien mailing list