Dear Stefaan Cottenier Sir,<div><br></div><div> Thank you very much for your reply. It resolves all of our doubts. </div><div><br></div><div>with best regards,</div><div><br></div><div>
Shamik Chakrabarti<br><br><div class="gmail_quote">On Fri, Dec 10, 2010 at 3:43 PM, Stefaan Cottenier <span dir="ltr"><<a href="mailto:Stefaan.Cottenier@ugent.be">Stefaan.Cottenier@ugent.be</a>></span> wrote:<br><blockquote class="gmail_quote" style="margin:0 0 0 .8ex;border-left:1px #ccc solid;padding-left:1ex;">
<div class="im"><br>
<blockquote class="gmail_quote" style="margin:0 0 0 .8ex;border-left:1px #ccc solid;padding-left:1ex">
We have done a calculation for a material<br>
having space group *Pnma.* The material has *4 in equivalent* atoms and<br>
total *20 atoms/unit cell*. Now if we use all the 20 atomic coordinates<br>
of previous calculation and make *all of them inequivalent by changing<br>
the space group to Primitive* then whether the calculation will give the<br>
same results as earlier calculation??.....I am asking this question<br>
because the structure (in Xcrysden) seems to be different.........<br>
</blockquote>
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A static calculation (one scf-cycle) must give you the same result, yes. It will only take more time, because one can profit less from symmetry.<br>
<br>
If you allow geometry optimization, the final geometry might be different, however: perhaps an atom that is not longer constrained by symmetry might want to move to a different place.<br>
<br>
In order to convince yourself whether or not both structures are identical, it is much cheaper to inspect the neighbours rather than performing an scf cycle. Do 'x nn' for both structures, and compare the distances in case.outputnn.<br>
<br>
Stefaan<br>
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</blockquote></div><br><br clear="all"><br>-- <br>Shamik Chakrabarti<br>Research Scholar<br>Dept. of Physics & Meteorology<br>Material Processing & Solid State Ionics Lab<br>IIT Kharagpur<br>Kharagpur 721302<br>INDIA<br>
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