<div dir="ltr"><div><div><div><div><div><div><div>Hello List,<br><br><br></div>For a complex system, I am getting below warnings (wien2k_17.1):<br><br><span class="gmail-gr_ gmail-gr_49 gmail-gr-alert gmail-gr_gramm gmail-gr_inline_cards gmail-gr_disable_anim_appear gmail-Style gmail-replaceWithoutSep" id="gmail-49"></span><div><span class="gmail-gr_ gmail-gr_106 gmail-gr-alert gmail-gr_gramm gmail-gr_inline_cards gmail-gr_disable_anim_appear gmail-Style gmail-replaceWithoutSep gmail-gr-progress" id="gmail-106">:WARN</span><br><br></div><div><span class="gmail-gr_ gmail-gr_37 gmail-gr-alert gmail-gr_gramm gmail-gr_inline_cards gmail-gr_disable_anim_appear gmail-Style gmail-replaceWithoutSep" id="gmail-37">:WARNING</span> Sum of forces not small, possible numerical issues<br><span class="gmail-gr_ gmail-gr_39 gmail-gr-alert gmail-gr_gramm gmail-gr_inline_cards gmail-gr_disable_anim_appear gmail-Style gmail-replaceWithoutSep" id="gmail-39">:</span><span class="gmail-gr_ gmail-gr_40 gmail-gr-alert gmail-gr_gramm gmail-gr_inline_cards gmail-gr_disable_anim_appear gmail-Style gmail-multiReplace" id="gmail-40"><span class="gmail-gr_ gmail-gr_38 gmail-gr-alert gmail-gr_gramm gmail-gr_inline_cards gmail-gr_disable_anim_appear gmail-Punctuation gmail-only-del gmail-replaceWithoutSep" id="gmail-38"><span class="gmail-gr_ gmail-gr_39 gmail-gr-alert gmail-gr_gramm gmail-gr_inline_cards gmail-gr_disable_anim_appear gmail-Style gmail-replaceWithoutSep" id="gmail-39">WARN</span> :</span></span> QTL-B value eq. 2.79 in Band of energy -0.76594 ATOM= 7 L= 0<br><span class="gmail-gr_ gmail-gr_41 gmail-gr-alert gmail-gr_gramm gmail-gr_inline_cards gmail-gr_disable_anim_appear gmail-Style gmail-replaceWithoutSep" id="gmail-41">:</span><span class="gmail-gr_ gmail-gr_42 gmail-gr-alert gmail-gr_gramm gmail-gr_inline_cards gmail-gr_disable_anim_appear gmail-Style gmail-multiReplace" id="gmail-42"><span class="gmail-gr_ gmail-gr_41 gmail-gr-alert gmail-gr_gramm gmail-gr_inline_cards gmail-gr_disable_anim_appear gmail-Style gmail-replaceWithoutSep" id="gmail-41">WARN</span> :</span> You should change the E-parameter for this atom and L-value in case.in1 (or try the -in1new<br><span class="gmail-gr_ gmail-gr_44 gmail-gr-alert gmail-gr_gramm gmail-gr_inline_cards gmail-gr_disable_anim_appear gmail-Style gmail-replaceWithoutSep" id="gmail-44">:</span><span class="gmail-gr_ gmail-gr_45 gmail-gr-alert gmail-gr_gramm gmail-gr_inline_cards gmail-gr_disable_anim_appear gmail-Style gmail-multiReplace" id="gmail-45"><span class="gmail-gr_ gmail-gr_43 gmail-gr-alert gmail-gr_gramm gmail-gr_inline_cards gmail-gr_disable_anim_appear gmail-Punctuation gmail-only-del gmail-replaceWithoutSep" id="gmail-43"><span class="gmail-gr_ gmail-gr_44 gmail-gr-alert gmail-gr_gramm gmail-gr_inline_cards gmail-gr_disable_anim_appear gmail-Style gmail-replaceWithoutSep" id="gmail-44">WARN</span> :</span></span> QTL-B value eq. 3.90 in Band of energy -0.76610 ATOM= 12 L= 0<br><span class="gmail-gr_ gmail-gr_46 gmail-gr-alert gmail-gr_gramm gmail-gr_inline_cards gmail-gr_disable_anim_appear gmail-Style gmail-replaceWithoutSep" id="gmail-46">:WARNING</span> Sum of forces not small, possible numerical issues<br><span class="gmail-gr_ gmail-gr_47 gmail-gr-alert gmail-gr_gramm gmail-gr_inline_cards gmail-gr_disable_anim_appear gmail-Style gmail-replaceWithoutSep" id="gmail-47">:WARNING</span> Sum of forces not small, possible numerical issues<br><span class="gmail-gr_ gmail-gr_48 gmail-gr-alert gmail-gr_gramm gmail-gr_inline_cards gmail-gr_disable_anim_appear gmail-Style gmail-replaceWithoutSep" id="gmail-48">:WARNING</span> Sum of forces not small, possible numerical issues<br><span class="gmail-gr_ gmail-gr_49 gmail-gr-alert gmail-gr_gramm gmail-gr_inline_cards gmail-gr_disable_anim_appear gmail-Style gmail-replaceWithoutSep" id="gmail-49">:WARNING</span> Sum of forces not small, possible numerical issues<br><span class="gmail-gr_ gmail-gr_50 gmail-gr-alert gmail-gr_gramm gmail-gr_inline_cards gmail-gr_disable_anim_appear gmail-Style gmail-replaceWithoutSep" id="gmail-50">:WARNING</span> Sum of forces not small, possible numerical issues >>> FGL forces are mentioned at the end of this email.</div><br><br><div><div><br>--------------------------------------------------------------<br><br></div><div>My queries are:<br><br><br></div>As QTL-B is not occurring after the first cycle, what about I should worry? <br><br></div><span class="gmail-gr_ gmail-gr_31 gmail-gr-alert gmail-gr_gramm gmail-gr_inline_cards gmail-gr_disable_anim_appear gmail-Style gmail-replaceWithoutSep" id="gmail-31">:FOR</span> command is not giving anything in output.<br>-----------------------------------------------------<br><br></div><div>:ENE<br><br></div><div>:ENE : *WARNING** TOTAL ENERGY IN Ry = -141317.23075973<br>:ENE : *WARNING** TOTAL ENERGY IN Ry = -141317.14726532<br>:ENE : *WARNING** TOTAL ENERGY IN Ry = -141317.11826684<br>:ENE : *WARNING** TOTAL ENERGY IN Ry = -141317.03718321<br>:ENE : *WARNING** TOTAL ENERGY IN Ry = -141316.82361906<br>:ENE : *WARNING** TOTAL ENERGY IN Ry = -141316.63199146<br><br><br> :DIS <br><br>:DIS : CHARGE DISTANCE ( 0.641253 for atom 36 spin 1) 0.204548<br>:DIS : CHARGE DISTANCE ( 0.635240 for atom 34 spin 1) 0.198777<br>:DIS : CHARGE DISTANCE ( 0.577491 for atom 36 spin 1) 0.189881<br>:DIS : CHARGE DISTANCE ( 0.525253 for atom 34 spin 1) 0.179297<br>:DIS : CHARGE DISTANCE ( 0.382213 for atom 13 spin 1) 0.146385<br>:DIS : CHARGE DISTANCE ( 0.238821 for atom 15 spin 1) 0.107937<br><br></div><br></div><br><br></div><br></div>below is constructive output from six scf cycles:<br><br>:DIRT : |MSR1a|= 1.528E-01 |PRATT|= 9.673E+00 ANGLE= 3.1 DEGREES<br>:ENE : *WARNING** TOTAL ENERGY IN Ry = -141317.14726532<br>:FER : F E R M I - ENERGY(TETRAH.M.)= 0.1272770189<br>:DIS : CHARGE DISTANCE ( 0.577491 for atom 36 spin 1) 0.189881<br>:PLANE: INTERSTITIAL TOTAL 4.53645 RMS 8.221E+01 , 2.804E+01 %<br>:CHARG: CLM CHARGE /ATOM 27.43229 RMS 2.659E+00 , 6.171E-01 %<br>:ADIST Largest Distance 1.71E+02 mau for atom 18<br>:RANK : ACTIVE 2.00/2 = 99.94 %<br>:DIRM : MEMORY 2/12 RESCALES 5.15 1.12 RED 0.97 PRED 1.00 NEXT 0.97 <br>:DIRA : |MSR1a|= 5.941E-02 |PRATT|= 2.815E+00 ANGLE= 0.7 DEGREES<br>:DIRP : |MSR1a|= 1.294E-01 |PRATT|= 6.546E+00 ANGLE= 20.4 DEGREES<br>:DIRQ : |MSR1a|= 1.296E-01 |PRATT|= 6.094E+00 ANGLE= 3.9 DEGREES<br>:DIRT : |MSR1a|= 1.925E-01 |PRATT|= 9.376E+00 ANGLE= 14.3 DEGREES<br>:ENE : *WARNING** TOTAL ENERGY IN Ry = -141317.11826684<br>:FER : F E R M I - ENERGY(TETRAH.M.)= 0.1257022001<br>:DIS : CHARGE DISTANCE ( 0.525253 for atom 34 spin 1) 0.179297<br>:PLANE: INTERSTITIAL TOTAL 4.52382 RMS 8.031E+01 , 2.750E+01 %<br>:CHARG: CLM CHARGE /ATOM 27.43228 RMS 2.507E+00 , 5.819E-01 %<br>:ADIST Largest Distance 1.67E+02 mau for atom 32<br>:RANK : ACTIVE 3.00/3 = 99.98 %<br>:DIRM : MEMORY 3/12 RESCALES 5.04 1.13 RED 0.94 PRED 0.97 NEXT 0.99 <br>:DIRA : |MSR1a|= 1.765E-01 |PRATT|= 2.608E+00 ANGLE= 0.5 DEGREES<br>:DIRP : |MSR1a|= 4.183E-01 |PRATT|= 6.269E+00 ANGLE= 8.1 DEGREES<br>:DIRQ : |MSR1a|= 3.882E-01 |PRATT|= 5.746E+00 ANGLE= 2.7 DEGREES<br>:DIRT : |MSR1a|= 5.974E-01 |PRATT|= 8.895E+00 ANGLE= 6.0 DEGREES<br>:ENE : *WARNING** TOTAL ENERGY IN Ry = -141317.03718321<br>:FER : F E R M I - ENERGY(TETRAH.M.)= 0.1208993370<br>:DIS : CHARGE DISTANCE ( 0.382213 for atom 13 spin 1) 0.146385<br>:PLANE: INTERSTITIAL TOTAL 4.48006 RMS 7.607E+01 , 2.638E+01 %<br>:CHARG: CLM CHARGE /ATOM 27.43218 RMS 2.059E+00 , 4.777E-01 %<br>:ADIST Largest Distance 1.20E+02 mau for atom 32<br>:RANK : ACTIVE 4.00/4 = 99.98 %<br>:DIRM : MEMORY 4/12 RESCALES 4.84 1.16 RED 0.84 PRED 0.99 NEXT 0.60 <br>:DIRA : |MSR1a|= 2.508E-01 |PRATT|= 1.991E+00 ANGLE= 0.9 DEGREES<br>:DIRP : |MSR1a|= 7.533E-01 |PRATT|= 5.715E+00 ANGLE= 2.0 DEGREES<br>:DIRQ : |MSR1a|= 5.981E-01 |PRATT|= 4.718E+00 ANGLE= 3.4 DEGREES<br>:DIRT : |MSR1a|= 9.940E-01 |PRATT|= 7.673E+00 ANGLE= 2.8 DEGREES<br>:ENE : *WARNING** TOTAL ENERGY IN Ry = -141316.82361906<br>:FER : F E R M I - ENERGY(TETRAH.M.)= 0.1150312568<br>:DIS : CHARGE DISTANCE ( 0.238821 for atom 15 spin 1) 0.107937<br>:PLANE: INTERSTITIAL TOTAL 4.39709 RMS 6.898E+01 , 2.447E+01 %<br>:CHARG: CLM CHARGE /ATOM 27.43198 RMS 1.485E+00 , 3.444E-01 %<br>:ADIST Largest Distance 5.87E+01 mau for atom 32<br>:RANK : ACTIVE 4.94/5 = 98.71 %<br>:DIRM : MEMORY 5/12 RESCALES 4.52 1.22 RED 0.77 PRED 0.60 NEXT 0.55 <br>:DIRA : |MSR1a|= 2.637E-01 |PRATT|= 1.172E+00 ANGLE= 4.0 DEGREES<br>:DIRP : |MSR1a|= 9.956E-01 |PRATT|= 4.863E+00 ANGLE= 10.2 DEGREES<br>:DIRQ : |MSR1a|= 7.110E-01 |PRATT|= 3.401E+00 ANGLE= 5.3 DEGREES<br>:DIRT : |MSR1a|= 1.252E+00 |PRATT|= 6.049E+00 ANGLE= 8.8 DEGREES<br>:ENE : *WARNING** TOTAL ENERGY IN Ry = -141316.63199146<br><br><br><br> TOTAL FORCE WITH RESPECT TO THE GLOBAL COORDINATE SYSTEM:<br>:FGL001: 1.ATOM 0.571294427 -0.984395898 -10.156208280 total forces<br>:FGL002: 2.ATOM 1.343645319 0.091427999 -10.261172923 total forces<br>:FGL003: 3.ATOM -1.285390107 -1.903206462 -9.764614672 total forces<br>:FGL004: 4.ATOM -21.041996528 17.357877607 0.427363571 total forces<br>:FGL005: 5.ATOM -18.604832579 -37.384671309 -2.411184844 total forces<br>:FGL006: 6.ATOM 39.143682535 16.539145810 -3.750206793 total forces<br>:FGL007: 7.ATOM -15.676184785 24.497070389 -1.206071928 total forces<br>:FGL008: 8.ATOM -13.768870206 -39.803728095 -3.694209515 total forces<br>:FGL009: 9.ATOM 35.314925201 14.961915477 -2.607881426 total forces<br>:FGL010: 10.ATOM -17.529305313 21.247241665 -0.259819059 total forces<br>:FGL011: 11.ATOM -15.806428886 -37.411247682 -1.990532754 total forces<br>:FGL012: 12.ATOM 39.515957536 16.971075693 -4.163396944 total forces<br>:FGL013: 13.ATOM 17.036126682 30.955115897 50.007968183 total forces<br>:FGL014: 14.ATOM -27.381314606 15.197774473 50.627297378 total forces<br>:FGL015: 15.ATOM -27.171090470 15.309775324 50.678251826 total forces<br>:FGL016: 16.ATOM -59.416593432 126.064160541 51.099204694 total forces<br>:FGL017: 17.ATOM 146.172448197 225.245325043 -100.156043401 total forces<br>:FGL018: 18.ATOM -228.797027515 -110.869626478 -69.426077373 total forces<br>:FGL019: 19.ATOM 73.272838167 -128.381818870 -39.564568505 total forces<br>:FGL020: 20.ATOM 187.496164199 85.129581199 45.883190907 total forces<br>:FGL021: 21.ATOM 186.781832051 94.129704150 85.662229642 total forces<br>:FGL022: 22.ATOM -130.761418027 -183.213519011 67.710470188 total forces<br>:FGL023: 23.ATOM -80.621948916 105.787918775 34.000048113 total forces<br>:FGL024: 24.ATOM 160.278146800 222.343005595 -80.389974363 total forces<br>:FGL025: 25.ATOM -226.720800060 -116.863011011 -103.374227364 total forces<br>:FGL026: 26.ATOM 85.838198132 -113.446334524 -30.995964330 total forces<br>:FGL027: 27.ATOM -110.313416958 -185.124670171 87.710943005 total forces<br>:FGL028: 28.ATOM 186.785307061 94.210187204 85.794580642 total forces<br>:FGL029: 29.ATOM -130.737727764 -183.326349898 67.616110857 total forces<br>:FGL030: 30.ATOM -80.610399226 105.940364776 34.065809549 total forces<br>:FGL031: 31.ATOM 160.346586523 222.211490035 -80.421260714 total forces<br>:FGL032: 32.ATOM -226.976448646 -116.960741470 -103.268914927 total forces<br>:FGL033: 33.ATOM 85.748222061 -113.173598661 -30.857799152 total forces<br>:FGL034: 34.ATOM 15.742345561 -7.390585563 -21.137999944 total forces<br>:FGL035: 35.ATOM -6.064680531 -16.016974778 -18.722699858 total forces<br>:FGL036: 36.ATOM 16.182253482 -7.265497659 -20.910887856 total forces<br>:FCHECK: Sum of forces -1.715900623 54.670180112 -38.208248369<br><br><br><br></div>regards<br><br></div>Bhamu<br clear="all"><div><div><div><div><div><div><div><div><div><div><div class="gmail_signature"><div dir="ltr"><div><div dir="ltr"><div dir="ltr"><div dir="ltr"><div dir="ltr"><br></div></div></div></div></div></div></div></div>
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