<div dir="ltr">Dear Prof. Blaha,<br><div><br></div><div>                     Thank you Sir. I will try this.</div><div><br></div><div>with regards,</div></div><br><div class="gmail_quote"><div dir="ltr" class="gmail_attr">On Tue, 20 Jul 2021 at 17:19, Peter Blaha <<a href="mailto:pblaha@theochem.tuwien.ac.at">pblaha@theochem.tuwien.ac.at</a>> wrote:<br></div><blockquote class="gmail_quote" style="margin:0px 0px 0px 0.8ex;border-left:1px solid rgb(204,204,204);padding-left:1ex">No, this energy difference is NOT the activation energy. You need to <br>
find the transition state.<br>
<br>
In the mixer there is a nice option, namely to use a constraint.<br>
With this option you can eg. drive an atom from (X1,y1,z1) to a final <br>
position, with the constraint that eg. the z1 coordinate should increase <br>
to a certain value z2 (corresponding to the final state). x2,y2 will <br>
follow the forces and get optimized (provided the movement along z is <br>
not too fast.<br>
<br>
It works quite well, once you have found the proper parameters driving <br>
the movement via some pseudoforces.<br>
<br>
Please checkout in SRC_mixer the corresponding doku.<br>
<br>
Am 20.07.2021 um 13:26 schrieb shamik chakrabarti:<br>
> Dear Prof. Laurence,<br>
> <br>
>                      Thank you for your response. If I know the initial <br>
> & final step & if we just check the difference in energy of those two <br>
> steps, whether the difference in energy can be taken as activation energy?<br>
> <br>
> with regards,<br>
> <br>
> On Tue, 20 Jul 2021 at 16:51, Laurence Marks <<a href="mailto:laurence.marks@gmail.com" target="_blank">laurence.marks@gmail.com</a> <br>
> <mailto:<a href="mailto:laurence.marks@gmail.com" target="_blank">laurence.marks@gmail.com</a>>> wrote:<br>
> <br>
>     If you can isolate the transition state, e.g. by symmetry, then you<br>
>     can do it directly. Otherwise there is no NEB currently in Wien2k.<br>
> <br>
>     _____<br>
>     Professor Laurence Marks<br>
>     "Research is to see what everybody else has seen, and to think what<br>
>     nobody else has thought", Albert Szent-Györgyi<br>
>     <a href="http://www.numis.northwestern.edu" rel="noreferrer" target="_blank">www.numis.northwestern.edu</a> <<a href="http://www.numis.northwestern.edu" rel="noreferrer" target="_blank">http://www.numis.northwestern.edu</a>><br>
> <br>
>     On Tue, Jul 20, 2021, 06:03 shamik chakrabarti<br>
>     <<a href="mailto:shamik15041981@gmail.com" target="_blank">shamik15041981@gmail.com</a> <mailto:<a href="mailto:shamik15041981@gmail.com" target="_blank">shamik15041981@gmail.com</a>>> wrote:<br>
> <br>
>         Dear Wien2k users,<br>
> <br>
>                              Is it possible to compute the activation<br>
>         energy of hopping of Li/Na in an electrode material by using wien2k?<br>
> <br>
>         Any response will be appreciated.<br>
> <br>
>         with regards,<br>
> <br>
>         -- <br>
>         Dr. Shamik Chakrabarti<br>
>         Research Fellow<br>
>         Department of Physics<br>
>         Indian Institute of Technology Patna<br>
>         Bihta-801103<br>
>         Patna<br>
>         Bihar, India<br>
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> <br>
> <br>
> <br>
> -- <br>
> Dr. Shamik Chakrabarti<br>
> Research Fellow<br>
> Department of Physics<br>
> Indian Institute of Technology Patna<br>
> Bihta-801103<br>
> Patna<br>
> Bihar, India<br>
> <br>
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> <br>
<br>
-- <br>
--------------------------------------------------------------------------<br>
Peter BLAHA, Inst.f. Materials Chemistry, TU Vienna, A-1060 Vienna<br>
Phone: +43-1-58801-165300             FAX: +43-1-58801-165982<br>
Email: <a href="mailto:blaha@theochem.tuwien.ac.at" target="_blank">blaha@theochem.tuwien.ac.at</a>    WIEN2k: <a href="http://www.wien2k.at" rel="noreferrer" target="_blank">http://www.wien2k.at</a><br>
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</blockquote></div><br clear="all"><div><br></div>-- <br><div dir="ltr" class="gmail_signature"><div dir="ltr"><div><div dir="ltr"><div dir="ltr"><div dir="ltr"><div dir="ltr"><div style="font-size:small">Dr. Shamik Chakrabarti</div><div style="font-size:small">Research Fellow </div><div style="font-size:small">Department of Physics</div><div style="font-size:small">Indian Institute of Technology Patna</div><div style="font-size:small">Bihta-801103</div><div style="font-size:small">Patna</div><div style="font-size:small">Bihar, India</div></div></div></div></div></div></div></div>