[Wien] DOS is empty and bandranges are zero

Thomas Claesson tcl at kth.se
Mon May 30 10:15:30 CEST 2005


Dear Wien users and developers!

I am running WIEN2k_04.10 (Release 8/10/2004) on a Red Har Linux system
using the precompiled binaries. I want to calculate and plot the
bandstructure and DOS of my case, which is a hypothetical AF NiO
structure. I am running the scf cycle with runsp_lapw (no extra
switches). XC-potential: 'GGA of Perdew-Burke-Ernzerhof 96' size of
k-mesh: 10 k-points.

I can initialize my case and run it to self-consistency without getting
any warnings or error messages. Wien2k finds the Fermi energy and
produces a plausible bandstructure in the GAMMA-X direction. I have
flipped the spin up and dn populations case.inst for the start density
and :MMTOT is converging towards zero as expected. However, when I try
to plot DOS it is completely empty (zero everywhere). And when I look in
case.output2(up/dn) I find that the bandranges for all bands are zero,
i.e. emax = emin for all bands. How is this possible when there is a lot
of dispersion in the plot produced by spaghetti? I have not made any
changes to the default case.in1 or case.in2 pruduced during the
initializing sequence. My guess is that something is wrong with one or
both of these input files. Or could it be that am I using too few k-points?

Below I attach the relevant input and output files (case.struct,
case.in1, case.in2, case.output2up, case.outputtup)

Thanks for your replies!

Any suggestions are welcome! Please let me know if you need more
information from me (like case.scf, case.outputsp or other files  ...)
to understand this problem.

Best regards,
Thomas Claesson


**********************************************************

case.struct:

NiO

P   LATTICE,NONEQUIV.ATOMS:  6 10 P2/m

MODE OF CALC=RELA unit=bohr

   9.674331 11.170955  5.585477 90.000000 90.000000125.264389

ATOM  -1: X=0.00000000 Y=0.00000000 Z=0.00000000
           MULT= 1          ISPLIT= 8
Ni1        NPT=  781  R0=0.00050000 RMT=    2.0000   Z: 28.0

LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                      0.0000000 1.0000000 0.0000000
                      0.0000000 0.0000000 1.0000000
ATOM  -2: X=0.00000000 Y=0.50000000 Z=0.00000000
           MULT= 1          ISPLIT= 8
Ni2        NPT=  781  R0=0.00050000 RMT=    2.0000   Z: 28.0

LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                      0.0000000 1.0000000 0.0000000
                      0.0000000 0.0000000 1.0000000
ATOM  -3: X=0.50000000 Y=0.00000000 Z=0.50000000
           MULT= 1          ISPLIT= 8
Ni3        NPT=  781  R0=0.00050000 RMT=    2.0000   Z: 28.0

LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                      0.0000000 1.0000000 0.0000000
                      0.0000000 0.0000000 1.0000000
ATOM  -4: X=0.50000000 Y=0.50000000 Z=0.50000000
           MULT= 1          ISPLIT= 8
Ni4        NPT=  781  R0=0.00050000 RMT=    2.0000   Z: 28.0

LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                      0.0000000 1.0000000 0.0000000
                      0.0000000 0.0000000 1.0000000
ATOM  -5: X=0.50000000 Y=0.25000000 Z=0.00000000
           MULT= 2          ISPLIT= 8
       -5: X=0.50000000 Y=0.75000000 Z=0.00000000
O 1        NPT=  781  R0=0.00050000 RMT=    1.7500   Z:  8.0

LOCAL ROT MATRIX:    1.0000000 0.0000000 0.0000000
                      0.0000000 1.0000000 0.0000000
                      0.0000000 0.0000000 1.0000000
ATOM  -6: X=0.00000000 Y=0.75000000 Z=0.50000000
           MULT= 2          ISPLIT= 8
       -6: X=0.00000000 Y=0.25000000 Z=0.50000000
O 2        NPT=  781  R0=0.00050000 RMT=    1.7500   Z:  8.0


**************************************************************

case.in1:

WFFIL        (WFPRI, SUPWF)
   7.00       10    4 (R-MT*K-MAX; MAX L IN WF, V-NMT
   0.30    4  0      (GLOBAL E-PARAMETER WITH n OTHER CHOICES, global
APW/LAPW)
  1    0.30      0.000 CONT 1
  1   -4.96      0.005 STOP 1
  2    0.30      0.010 CONT 1
  0    0.30      0.000 CONT 1
   0.30    4  0      (GLOBAL E-PARAMETER WITH n OTHER CHOICES, global
APW/LAPW)
  1    0.30      0.000 CONT 1
  1   -4.80      0.005 STOP 1
  2    0.30      0.010 CONT 1
  0    0.30      0.000 CONT 1
   0.30    4  0      (GLOBAL E-PARAMETER WITH n OTHER CHOICES, global
APW/LAPW)
  1    0.30      0.000 CONT 1
  1   -4.96      0.005 STOP 1
  2    0.30      0.010 CONT 1
  0    0.30      0.000 CONT 1
   0.30    4  0      (GLOBAL E-PARAMETER WITH n OTHER CHOICES, global
APW/LAPW)
  1    0.30      0.000 CONT 1
  1   -4.80      0.005 STOP 1
  2    0.30      0.010 CONT 1
  0    0.30      0.000 CONT 1
   0.30    3  0      (GLOBAL E-PARAMETER WITH n OTHER CHOICES, global
APW/LAPW)
  0   -1.55      0.010 CONT 1
  0    0.30      0.000 CONT 1
  1    0.30      0.000 CONT 1
   0.30    3  0      (GLOBAL E-PARAMETER WITH n OTHER CHOICES, global
APW/LAPW)
  0   -1.55      0.010 CONT 1
  0    0.30      0.000 CONT 1
  1    0.30      0.000 CONT 1
K-VECTORS FROM UNIT:4   -7.0       1.5      emin/emax window

*********************************************************************

case.in2:


TOT             (TOT,FOR,QTL,EFG,FERMI)
       -9.0      88.0 0.50 0.05                EMIN, NE, ESEPERMIN, ESEPER0
TETRA    0.000          (GAUSS,ROOT,TEMP,TETRA,ALL      eval)
   0 0  2 0  2 2 -2 2  4 0  4 2 -4 2  4 4 -4 4  6 0  6 2 -6 2  6 4 -6 4
  6 6 -6 6
   0 0  2 0  2 2 -2 2  4 0  4 2 -4 2  4 4 -4 4  6 0  6 2 -6 2  6 4 -6 4
  6 6 -6 6
   0 0  2 0  2 2 -2 2  4 0  4 2 -4 2  4 4 -4 4  6 0  6 2 -6 2  6 4 -6 4
  6 6 -6 6
   0 0  2 0  2 2 -2 2  4 0  4 2 -4 2  4 4 -4 4  6 0  6 2 -6 2  6 4 -6 4
  6 6 -6 6
   0 0  1 1 -1 1  2 0  2 2 -2 2  3 1 -3 1  3 3 -3 3  4 0  4 2 -4 2  4 4
-4 4  5 1 -5 1  5 3 -5 3  5 5 -5 5  6 0  6 2 -6 2  6 4 -6 4  6 6 -6 6
   0 0  1 1 -1 1  2 0  2 2 -2 2  3 1 -3 1  3 3 -3 3  4 0  4 2 -4 2  4 4
-4 4  5 1 -5 1  5 3 -5 3  5 5 -5 5  6 0  6 2 -6 2  6 4 -6 4  6 6 -6 6
  14.          GMAX
FILE        FILE/NOFILE  write recprlist

***************************************************************************

case.output2up:

  Running LAPW2 in single processor mode

   Modus: TOT
  no read error
  RECPR LIST: FILE





--------------------------------------------------
                                  S T R U C T U R A L   I N F O R M A T
I O N

--------------------------------------------------


    SUBSTANCE                    = NiO


    LATTICE                      = P
    LATTICE CONSTANTS ARE        =    9.6743310  11.1709550   5.5854770
    NUMBER OF ATOMS IN UNITCELL  =   6
    MODE OF CALCULATION IS       = RELA
    TYPE OF COORDINATES IN DSPLIT=
  reading recprlist from file
    BZ-integration with TETRA-program. icor=:           1
  call eord...
  call dos...
    FERMI ENERGY AT   0.4897652208544909
    SUM RULE OF TETRAHEDRON INTEGRATION CHECKED
  call eweigh...
    number of occupied bands:          44
    highest energy:  0.4866637317612166

  Bandranges (emin - emax):
  band           1  -4.223602868869058       -4.223602868869058
  band           2  -4.223357755608264       -4.223357755608264
  band           3  -4.223265432887361       -4.223265432887361
  band           4  -4.223034145251924       -4.223034145251924
  band           5  -4.208316267947989       -4.208316267947989
  band           6  -4.207854147874764       -4.207854147874764
  band           7  -4.096703236946777       -4.096703236946777
  band           8  -4.095973060863754       -4.095973060863754
  band           9  -4.095784007635840       -4.095784007635840
  band          10  -4.095457783903152       -4.095457783903152
  band          11  -4.095264216540885       -4.095264216540885
  band          12  -4.095225418256874       -4.095225418256874
  band          13 -0.8888831877608215      -0.8888831877608215
  band          14 -0.8525961078713195      -0.8525961078713195
  band          15 -0.8525910811188137      -0.8525910811188137
  band          16 -0.8302355584640914      -0.8302355584640914
  band          17  2.0372206294521522E-002  2.0372206294521522E-002
  band          18  2.0885957364879193E-002  2.0885957364879193E-002
  band          19  7.5873657901876168E-002  7.5873657901876168E-002
  band          20  9.8238896712473878E-002  9.8238896712473878E-002
  band          21  9.8872272570013298E-002  9.8872272570013298E-002
  band          22  0.1235684909340891       0.1235684909340891
  band          23  0.1448276688653105       0.1448276688653105
  band          24  0.1449614859808359       0.1449614859808359
  band          25  0.1475734369783726       0.1475734369783726
  band          26  0.1494124391420661       0.1494124391420661
  band          27  0.2500459449008754       0.2500459449008754
  band          28  0.2510721651665784       0.2510721651665784
  band          29  0.3377008629273877       0.3377008629273877
  band          30  0.3937185807729739       0.3937185807729739
  band          31  0.3973213230488404       0.3973213230488404
  band          32  0.4005262975979710       0.4005262975979710
  band          33  0.4048306710645222       0.4048306710645222
  band          34  0.4077160471198664       0.4077160471198664
  band          35  0.4176324326671899       0.4176324326671899
  band          36  0.4328709084171183       0.4328709084171183
  band          37  0.4358610944233043       0.4358610944233043
  band          38  0.4428350497262161       0.4428350497262161
  band          39  0.4517268033866082       0.4517268033866082
  band          40  0.4644505935594885       0.4644505935594885
  band          41  0.4689545605568521       0.4689545605568521
  band          42  0.4755895070737206       0.4755895070737206
  band          43  0.4843671701628415       0.4843671701628415
  band          44  0.4866637317612166       0.4866637317612166
  band          45  0.5662129698809362       0.5662129698809362
  band          46  0.5856243052137109       0.5856243052137109
  band          47  0.6459990871859760       0.6459990871859760
  band          48  0.6519746681778513       0.6519746681778513
  band          49  0.9500812567039251       0.9500812567039251
  band          50   1.064816429760143        1.064816429760143
  band          51   1.065063693924019        1.065063693924019
  band          52   1.175747769196859        1.175747769196859
  band          53   1.333793708584221        1.333793708584221
  band          54   1.334995090665162        1.334995090665162
  band          55   1.351803549342354        1.351803549342354
  band          56   1.352011530518280        1.352011530518280
  band          57   1.364129162551853        1.364129162551853
  band          58   1.364154335406912        1.364154335406912

  eseper below EF  0.5000000000000000
  eseper minimum gap  5.0000000000000000E-002
  Energy to separate semicore and valence states: -2.9627793705478478E-002


:NOE  : NUMBER OF ELECTRONS          =  88.000

:FER  : F E R M I - ENERGY(TETRAH.M.)=   0.48977
  wmist   44.00000000003522
      FORCE-CALCULATION: F


--------------------------------------------------------------------
            W A V E F U N C T I O N S   AND   C H A R G E S   IN   S P H
E R E S

--------------------------------------------------------------------




:POS001: AT.NR.  -1 POSITION = 0.00000 0.00000 0.00000  MULTIPLICITY =  1


    NOT EQUIV ATOM Ni1         LOCAL ROTATION MATRIX
                                  1.00000   0.00000   0.00000
                                  0.00000   1.00000   0.00000
                                  0.00000   0.00000   1.00000
              EQUIV ATOM   1   POSITION:    0.000   0.000   0.000
                                  1.00000   0.00000   0.00000        0.00000
                                  0.00000   1.00000   0.00000        0.00000
                                  0.00000   0.00000   1.00000        0.00000

           ATOMIC PARAMETERS FOR Ni1

            ENERGY PARAMETERS ARE   0.30   0.30   0.31   0.30   0.30
0.30   0.30
            ENERGY PARAMETERS ARE   0.30   0.30


****************************************************************************


case.outputtup:


  Title

  IAV                         :  0
  NPRINT                      :  1
   5 CASES FOR DOS            :  ATOM   L
  CASE 1 :   ATOM NUMBER  0   COLUMN READ  0   DOSTYPE=total
  CASE 2 :   ATOM NUMBER  1   COLUMN READ  1   DOSTYPE=Atom1
  CASE 3 :   ATOM NUMBER  2   COLUMN READ  1   DOSTYPE=Atom1
  CASE 4 :   ATOM NUMBER  3   COLUMN READ  1   DOSTYPE=Atom1
  CASE 5 :   ATOM NUMBER  4   COLUMN READ  1   DOSTYPE=Atom2

  iO
  LATTICE CONST.= 9.6743011.17100 5.58550   FERMI ENERGY=   0.48990
   613 <; NMAT <;  613   SPIN=2   NATO= 7
  JATOM  1  MULT= 1  ISPLIT= 8
tot,0,1,PX,PY,PZ,2,DZ2,DX2Y2,DXY,DXZ,DYZ,3
  JATOM  2  MULT= 1  ISPLIT= 8
tot,0,1,PX,PY,PZ,2,DZ2,DX2Y2,DXY,DXZ,DYZ,3
  JATOM  3  MULT= 1  ISPLIT= 8
tot,0,1,PX,PY,PZ,2,DZ2,DX2Y2,DXY,DXZ,DYZ,3
  JATOM  4  MULT= 1  ISPLIT= 8
tot,0,1,PX,PY,PZ,2,DZ2,DX2Y2,DXY,DXZ,DYZ,3
  JATOM  5  MULT= 2  ISPLIT= 8
tot,0,1,PX,PY,PZ,2,DZ2,DX2Y2,DXY,DXZ,DYZ,3
  JATOM  6  MULT= 2  ISPLIT= 8
tot,0,1,PX,PY,PZ,2,DZ2,DX2Y2,DXY,DXZ,DYZ,3
  BAND LIMITS OF BAND  1 ARE  -4.22330  -4.22330
  BAND LIMITS OF BAND  2 ARE  -4.22302  -4.22302
  BAND LIMITS OF BAND  3 ARE  -4.22288  -4.22288
  BAND LIMITS OF BAND  4 ARE  -4.22265  -4.22265
  BAND LIMITS OF BAND  5 ARE  -4.20815  -4.20815
  BAND LIMITS OF BAND  6 ARE  -4.20772  -4.20772
  BAND LIMITS OF BAND  7 ARE  -4.09680  -4.09680
  BAND LIMITS OF BAND  8 ARE  -4.09612  -4.09612
  BAND LIMITS OF BAND  9 ARE  -4.09595  -4.09595
  BAND LIMITS OF BAND 10 ARE  -4.09562  -4.09562
  BAND LIMITS OF BAND 11 ARE  -4.09518  -4.09518
  BAND LIMITS OF BAND 12 ARE  -4.09515  -4.09515
  BAND LIMITS OF BAND 13 ARE  -0.88884  -0.88884
  BAND LIMITS OF BAND 14 ARE  -0.85256  -0.85256
  BAND LIMITS OF BAND 15 ARE  -0.85256  -0.85256
  BAND LIMITS OF BAND 16 ARE  -0.83021  -0.83021
  BAND LIMITS OF BAND 17 ARE   0.02043   0.02043
  BAND LIMITS OF BAND 18 ARE   0.02100   0.02100
  BAND LIMITS OF BAND 19 ARE   0.07595   0.07595
  BAND LIMITS OF BAND 20 ARE   0.09832   0.09832
  BAND LIMITS OF BAND 21 ARE   0.09896   0.09896
  BAND LIMITS OF BAND 22 ARE   0.12363   0.12363
  BAND LIMITS OF BAND 23 ARE   0.14494   0.14494
  BAND LIMITS OF BAND 24 ARE   0.14502   0.14502
  BAND LIMITS OF BAND 25 ARE   0.14764   0.14764
  BAND LIMITS OF BAND 26 ARE   0.14947   0.14947
  BAND LIMITS OF BAND 27 ARE   0.25009   0.25009
  BAND LIMITS OF BAND 28 ARE   0.25115   0.25115
  BAND LIMITS OF BAND 29 ARE   0.33787   0.33787
  BAND LIMITS OF BAND 30 ARE   0.39398   0.39398
  BAND LIMITS OF BAND 31 ARE   0.39776   0.39776
  BAND LIMITS OF BAND 32 ARE   0.40059   0.40059
  BAND LIMITS OF BAND 33 ARE   0.40489   0.40489
  BAND LIMITS OF BAND 34 ARE   0.40779   0.40779
  BAND LIMITS OF BAND 35 ARE   0.41765   0.41765
  BAND LIMITS OF BAND 36 ARE   0.43324   0.43324
  BAND LIMITS OF BAND 37 ARE   0.43628   0.43628
  BAND LIMITS OF BAND 38 ARE   0.44293   0.44293
  BAND LIMITS OF BAND 39 ARE   0.45169   0.45169
  BAND LIMITS OF BAND 40 ARE   0.46451   0.46451
  BAND LIMITS OF BAND 41 ARE   0.46883   0.46883
  BAND LIMITS OF BAND 42 ARE   0.47555   0.47555
  BAND LIMITS OF BAND 43 ARE   0.48440   0.48440
  BAND LIMITS OF BAND 44 ARE   0.48675   0.48675
  BAND LIMITS OF BAND 45 ARE   0.56612   0.56612
  BAND LIMITS OF BAND 46 ARE   0.58553   0.58553
  BAND LIMITS OF BAND 47 ARE   0.64598   0.64598
  BAND LIMITS OF BAND 48 ARE   0.65194   0.65194
  BAND LIMITS OF BAND 49 ARE   0.95018   0.95018
  BAND LIMITS OF BAND 50 ARE   1.06492   1.06492
  BAND LIMITS OF BAND 51 ARE   1.06521   1.06521
  BAND LIMITS OF BAND 52 ARE   1.17583   1.17583
  BAND LIMITS OF BAND 53 ARE   1.33395   1.33395
  BAND LIMITS OF BAND 54 ARE   1.33516   1.33516
  BAND LIMITS OF BAND 55 ARE   1.35195   1.35195
  BAND LIMITS OF BAND 56 ARE   1.35210   1.35210
  BAND LIMITS OF BAND 57 ARE   1.36431   1.36431
  BAND LIMITS OF BAND 58 ARE   1.36432   1.36432
   EMAX reduced due to lower HIGHEST BAND-minimum
  EMIN, DE, EMAX              :  -0.50000   0.00200   1.36432

   EMIN=  -0.50000 EMAX=   1.36432 EFACTR=    499.99996948 ESTEP =   0.00200
  ENERGY BAND    1 THROUGH   58 ENERGY CHANNEL:    1   TO  933
  NUMBER OF K-POINTS:           1
  NUMBER OF TETRAHEDRONS:           1
# Title
#EF=   0.48990     NDOS= 5     NENRG=  933    Gaussian bradening: 0.00300
  NUMBER OF ELECTRONS UP TO EF         :   28.0000

  DOS in states/Ry/spin
# ENERGY      0 total            1 Atom1            2 Atom1            3
Atom1            4 Atom2
  smearing           1  0.3989423       2.000000
  smearing           1  0.3989423       2.000000
  smearing           1  0.3989423       2.000000
  smearing           1  0.3989423       2.000000
  smearing           1  0.3989423       2.000000
  -0.50000     0.00   0.0000     0.00   0.0000     0.00   0.0000
0.00   0.0000     0.00   0.0000
  -0.49800     0.00   0.0000     0.00   0.0000     0.00   0.0000
0.00   0.0000     0.00   0.0000
  -0.49600     0.00   0.0000     0.00   0.0000     0.00   0.0000
0.00   0.0000     0.00   0.0000
  -0.49400     0.00   0.0000     0.00   0.0000     0.00   0.0000
0.00   0.0000     0.00   0.0000
  -0.49200     0.00   0.0000     0.00   0.0000     0.00   0.0000
0.00   0.0000     0.00   0.0000
  -0.49000     0.00   0.0000     0.00   0.0000     0.00   0.0000
0.00   0.0000     0.00   0.0000
  -0.48800     0.00   0.0000     0.00   0.0000     0.00   0.0000
0.00   0.0000     0.00   0.0000
  -0.48600     0.00   0.0000     0.00   0.0000     0.00   0.0000
0.00   0.0000     0.00   0.0000
  -0.48400     0.00   0.0000     0.00   0.0000     0.00   0.0000
0.00   0.0000     0.00   0.0000
  -0.48200     0.00   0.0000     0.00   0.0000     0.00   0.0000
0.00   0.0000     0.00   0.0000
  -0.48000     0.00   0.0000     0.00   0.0000     0.00   0.0000
0.00   0.0000     0.00   0.0000
  -0.47800     0.00   0.0000     0.00   0.0000     0.00   0.0000
0.00   0.0000     0.00   0.0000
  -0.47600     0.00   0.0000     0.00   0.0000     0.00   0.0000
0.00   0.0000     0.00   0.0000
  -0.47400     0.00   0.0000     0.00   0.0000     0.00   0.0000
0.00   0.0000     0.00   0.0000
  -0.47200     0.00   0.0000     0.00   0.0000     0.00   0.0000
0.00   0.0000     0.00   0.0000
  -0.47000     0.00   0.0000     0.00   0.0000     0.00   0.0000
0.00   0.0000     0.00   0.0000
  -0.46800     0.00   0.0000     0.00   0.0000     0.00   0.0000
0.00   0.0000     0.00   0.0000
  -0.46600     0.00   0.0000     0.00   0.0000     0.00   0.0000
0.00   0.0000     0.00   0.0000
  -0.46400     0.00   0.0000     0.00   0.0000     0.00   0.0000
0.00   0.0000     0.00   0.0000
  -0.46200     0.00   0.0000     0.00   0.0000     0.00   0.0000
0.00   0.0000     0.00   0.0000
  -0.46000     0.00   0.0000     0.00   0.0000     0.00   0.0000
0.00   0.0000     0.00   0.0000
  -0.45800     0.00   0.0000     0.00   0.0000     0.00   0.0000
0.00   0.0000     0.00   0.0000
  -0.45600     0.00   0.0000     0.00   0.0000     0.00   0.0000
0.00   0.0000     0.00   0.0000
  -0.45400     0.00   0.0000     0.00   0.0000     0.00   0.0000
0.00   0.0000     0.00   0.0000
  -0.45200     0.00   0.0000     0.00   0.0000     0.00   0.0000
0.00   0.0000     0.00   0.0000
  -0.45000     0.00   0.0000     0.00   0.0000     0.00   0.0000
0.00   0.0000     0.00   0.0000
  -0.44800     0.00   0.0000     0.00   0.0000     0.00   0.0000
0.00   0.0000     0.00   0.0000
  -0.44600     0.00   0.0000     0.00   0.0000     0.00   0.0000
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